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State the two forms of the second law of thermodynamics. - Chemistry

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State the two forms of the second law of thermodynamics.

Write statement of second law of thermodynamics.

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Solution

  1. Kelvin–Planck statement: Heat QH cannot be taken out of a hot reservoir and used in its whole for labour W. It is necessary for QC to exhaust (give away) some of its heat to a cold reservoir. This rules out the development of an ideal heat engine.
  2. Clausius statement: Heat cannot transfer from a colder body to a warmer body unless some effort is made to do this. This rules out the creation of the ideal refrigerator.
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Spontaneity - Entropy and Second Law of Thermodynamics
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