Advertisements
Advertisements
Question
Predict the type of cubic lattice of a solid element having edge length of 400 pm and density is 6.25 g/ml.
(Atomic mass of element = 60)
Advertisements
Solution
Given:
Edge length a = 400 pm = 400 × 10−12 m = 400 × 10−12 cm = 4 × 10−8 cm
a3 = (4 × 10−8 cm)3
= 64 × 10−24 cm3
ρ = 6.25 g/mL = 6.25 g.cm−3
M = 60
To find:
n = ?
Formula:
ρ = `("M"xx"n")/("a"^3xx"N"_"A")`
6.25 = `(60xx"n")/(64xx10^-24xx6.022xx10^23)`
6.25 = `(60xx"n")/(6.4xx6.022)`
n = `(6.25xx6.4xx6.022)/60`
n = `(6.25xx6.4)/10`
n = 4
Hence, the type of cubic lattice is FCC, as 4 particles are present per unit cell.
APPEARS IN
RELATED QUESTIONS
The coordination number of atoms in bcc crystal lattice is ______.
Answer the following in brief.
How are the spheres arranged in first layer of simple cubic close-packed structures? How are the successive layers of spheres placed above this layer?
How are tetrahedral and octahedral voids formed?
An octahedral void is surrounded by ________.
The number of tetrahedral voids are formed if the number of atoms in a crystal is N/2.
The number of octahedral voids formed in 0.5 mol of a compound forming hcp structure?
The ratio of close-packed atoms to tetrahedral holes in cubic close packing is ____________.
A metallic element crystallises in simple cubic lattice. If edge length of the unit cell is 3Å, with density 8 g/cc, what is the number of unit cells in 100 g of the metal?
(Molar mass of metal = 108 g/mol)
Xenon crystallises in fcc lattice and the edge length of unit cell is 620 pm. What is the radius of Xe atom?
The coordination number of each sphere in bcc lattice is ____________.
Which of the following is CORRECT for the two dimensional arrangement of spheres given below?

Zinc forms hcp structure. What is the number of tetrahedral voids formed in 0.3 mol of it?
The atoms of element 'Y' form hexagonal close packing and the atoms of element X occupies `3/4` th portion of the number of tetrahedral voids. The formula of the compound formed by X and Y is ____________.
Zinc forms hcp structure. What is the number of octahedral voids formed in 0.2 mol of it?
What is the coordination number of cation in ionic compound if the type of hole occupied by cation is octahedral?
Percentages of free space in cubic close-packed structure and in the body-centered packed structure are respectively ______.
Which metal crystallises in a simple cubic structure?
What is the coordination number of atoms in bcc crystal lattice?
The coordination number of cobalt in the complex [Co(en)2Br2]Cl2 is ______.
How much vacant space is present in hep crystal lattice?
Calculate the total number of tetrahedral and octahedral voids formed in 0.6 mol of a compound if it forms hcp structure.
Find the total number of tetrahedral and octahedral voids formed in 1 mole of a compound forming hcp structure.
