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Tamil Nadu Board of Secondary EducationHSC Science Class 11

Peroxide effect (Kharasch effect) can be studied in case of ______.

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Question

Peroxide effect (Kharasch effect) can be studied in case of ______.

Options

  • Oct – 4 – ene

  • hex – 3 – ene

  • pent – 1 – ene

  • but – 2 – ene

MCQ
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Solution

Peroxide effect (Kharasch effect) can be studied in case of pent – 1 – ene.

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Chapter 13: Hydrocarbons - Evaluation [Page 223]

APPEARS IN

Samacheer Kalvi Chemistry - Volume 1 and 2 [English] Class 11 TN Board
Chapter 13 Hydrocarbons
Evaluation | Q I. 29. | Page 223

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Which among the following alkenes on reductive ozonolysis produces only propanone?


\[\begin{array}{cc}
\phantom{......................................................}\ce{CH3}\phantom{............}\ce{Br}\phantom{}\\
\phantom{....................................................}|\phantom{.............}/\phantom{}\\
\ce{A + Mg ->[Dry][ether] CH3-Mg-Br + B ->[i. Dry ether][ii. H-OH/H^+] CH3-C-OH + Mg}\\
\phantom{.....................................................}|\phantom{.............}\backslash\phantom{}\\
\phantom{......................................................}\ce{CH3}\phantom{..........}\ce{OH}\phantom{}
\end{array}\]

Thus, 'B' in the above reaction is:


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\[\begin{array}{cc}
\phantom{..............................}\ce{CH3}\\\phantom{...........................}|\\\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3 - CH - CH2Br}\\
|\phantom{....................................}\\
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