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Question
Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzoyl (primary, secondary, tertiary), vinyl or aryl halide:
CH3C(Cl)(C2H5)CH2CH3
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Solution
\[\begin{array}{cc}
\ce{Cl}\phantom{......}\\
|\phantom{.......}\\
\ce{H3C - \underset{3}{C} - \underset{2}{C}H2 - \underset{1}{C}H3}\\
|\phantom{........}\\
\phantom{...}\ce{\underset{4}{C}H2 - \underset{5}{C}H3}\
\end{array}\]
IUPAC Name: 3-chloro-3-methylpentane
Classify: 3° alkyl halide
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RELATED QUESTIONS
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CH3CH2CH(CH3)CH(C2H5)Cl
Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzoyl (primary, secondary, tertiary), vinyl or aryl halide:
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Draw the structure of major monohalo product in each of the following reactions :
In which of the following molecules carbon atom marked with asterisk (*) is asymmetric?
(a) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{.}\ce{I}\phantom{...}\ce{Br}\phantom{..}\ce{Cl}
\end{array}\]
(b) \[\begin{array}{cc}
\ce{D}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{.}\ce{I}\phantom{...}\ce{Br}\phantom{..}\ce{Cl}
\end{array}\]
(c) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{..}\ce{OH}\phantom{..}\ce{C2H5}\phantom{}\ce{CH3}
\end{array}\]
(d) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{..}\ce{H}\phantom{...}\ce{C2H5}\phantom{}\ce{CH3}
\end{array}\]
The position of \[\ce{-Br}\] in the compound in \[\ce{CH3CH = CH(Br)(CH3)2}\] can be classified as ______.
Match the items of Column I and Column II.
| Column I | Column II | |
| (i) | SN1 reaction | (a) vic-dibromides |
| (ii) | Chemicals in fire extinguisher | (b) gem-dihalides |
| (iii) | Bromination of alkenes | (c) Racemisation |
| (iv) | Alkylidene halides | (d) Saytzeff rule |
| (v) | Elimination of HX from alkylhalide | (e) Chlorobromocarbons |
Match the structures of compounds given in Column I with the classes of compounds given in Column II.
| Column I | Column II | |
| (i) | \[\begin{array}{cc} \ce{CH3 - CH - CH3}\\ |\phantom{..}\\ \ce{X}\phantom{..} \end{array}\] |
(a) Aryl halide |
| (ii) | \[\ce{CH2 = CH - CH2 - X}\] | (b) Alkyl halide |
| (iii) |  |
(c) Vinyl halide |
| (iv) | \[\ce{CH2 = CH - X}\] | (d) Allyl halide |
Why are haloalkanes more reactive towards nucleophilic substitution reactions than haloarenes and vinylic halides?
Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
\[\ce{CH3C(C2H5)2CH2Br}\]
Name the following halides according to the IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
\[\ce{CH3C(C2H5)2CH2Br}\]
Name the following halides according to the IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
CH3C(C2H5 )2CH2Br
Name the following halide according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:
CH3C(Cl)(C2H5)CH2CH3
Name the following halide according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:
\[\ce{CH3C(C2H5)2CH2Br}\]
Name the following halide according to the IUPAC system and classify it as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:
\[\ce{CH_3CH_2C(CH_3)_2CH_2I}\]
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\[\ce{CH3C(Cl)(C2H5)CH2CH3}\]
Name the following halide according to IUPAC system and classify as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:
\[\ce{CH3C(C2H5)2CH2Br}\]
Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
\[\ce{CH3C(C2H5)2CH2Br}\]
Name the following halide according to IUPAC system and classify as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
\[\ce{CH3C(C2H5)2CH2Br}\]
Write the structure of the following organic halogen compound.
4-tert-Butyl-3-iodoheptane
