Advertisements
Advertisements
Question
In a pseudo first order hydrolysis of ester in water, the following results were obtained:
| t/s | 0 | 30 | 60 | 90 |
| [A]/mol L−1 | 0.55 | 0.31 | 0.17 | 0.085 |
Calculate the average rate of reaction between the time interval 30 to 60 seconds.
Advertisements
Solution
Average rate of reaction between the time interval, 30 to 60 seconds =
`(C_2 - C_1)/(t_2 - t_1)`
= `(0.17 - 0.31)/(60 - 30)`
= `(0.14)/30`
= -4.67 × 10−3 mol L−1 s−1
APPEARS IN
RELATED QUESTIONS
Sucrose decomposes in acid solution into glucose and fructose according to the first order rate law with `t_(1/2)` = 3 hours. What fraction of the sample of sucrose remains after 8 hours?
A first order reaction has a rate constant 1.15 × 10−3 s−1. How long will 5 g of this reactant take to reduce to 3 g?
For the decomposition of azoisopropane to hexane and nitrogen at 543 K, the following data are obtained.
| t (sec) | P(mm of Hg) |
| 0 | 35.0 |
| 360 | 54.0 |
| 720 | 63.0 |
Calculate the rate constant.
A first order reaction takes 20 minutes for 25% decomposition. Calculate the time when 75% of the reaction will be completed.
(Given : log = 2 = 0·3010, log 3 = 0·4771, log 4 = 0·6021)
Which of the following graphs is correct for a first order reaction?




State a condition under which a bimolecular reaction is kinetically first order reaction.
With the help of an example explain what is meant by pseudo first order reaction.
In the presence of acid, the initial concentration of cane sugar was reduced from 0.2 M to 0.1 Min 5 hours and to 0.05 Min 10 hours. The reaction must be of?
The rate constant of a first order reaction is 6.9 × 10–3s–1. How much time will it take to reduce the initial concentration to its 1/8th value?
First order reaction is 50% complete in 1.26 × 1014s. How much time could it take for 100% completion?
A first order reaction is 50% complete in 20 minute What is rate constant?
Observe the graph shown in figure and answer the following questions:

- What is the order of the reaction?
- What is the slope of the curve?
- Write the relationship between k and t1/2 (half life period).
Gaseous cyclobutene isomerizes to butadiene in a first order process which has a 'k' value of 3.3 × 10−4 s−1 at 153°C. The time in minutes it takes for the isomerization to proceed 40% to completion at this temperature is ______. (Rounded-off to the nearest integer)
A definite volume of H2O2 undergoing spontaneous decomposition required 22.8 c.c. of standard permanganate solution for titration. After 10 and 20 minutes respectively the volumes of permanganate required were 13.8 and 8.25 c.c. The time required for the decomposition to be half completed is ______ min.
The slope in the plot of ln[R] vs. time for a first order reaction is ______.
The slope in the plot of `log ["R"]_0/(["R"])` Vs. time for a first-order reaction is ______.
What is the rate constant?
Slove: \[\ce{2NOBr -> 2NO_{2(g)} + Br_{2(g)}}\]
For the above reaction, the rate law is rate = k[NOBr]2. If the rate of reaction is 6.5 × 10−6 mol L−1 s−1 at 2 × 10−3 mol L−1 concentration of NOBr, calculate the rate constant k for the reaction.
Write the equation for integrated rate law for a first order reaction.
