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Identify the Cations in the Following Case: Naoh Solution, When Added to the Solution (A), Gives a Reddish Brown Precipitate

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Question

Identify the cations in the following case:

NaOH solution, when added to the Solution (A), gives a reddish brown precipitate

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Solution

Fe3+ ion

FeCl3 + 3NaOH  Fe(OH)3 + 3NaCl

                                        (Reddish brown ppt.)

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Action of Sodium Hydroxide Solution on Certain Metallic Salt Solutions
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2015-2016 (March) Science Paper 2

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What do you observe when caustic soda solution is added to the following solution, first a little and then in excess:

ZnSO4

Write a balanced equation for this reaction.


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Name a white, insoluble oxide that dissolves when fused with caustic soda or caustic potash.


Sodium hydroxide solution is added to solution A. A white precipitate is formed which is soluble in excess sodium hydroxide. Name the metal ion present in A.


Three test tubes contain calcium nitrate solution, zinc nitrate solution and lead nitrate solution respectively. Each solution is divided into two portions (i) and (ii). Describe the effect of

  1. adding sodium hydroxide solution to each portion in turn till it is in excess.
  2. adding ammonium hydroxide to each portion in turn till it is in excess.

Choose the correct answer from the options given below :
Hydroxide of this metal is soluble is sodium hydroxide solution


A white solid A when heated with sodium hydroxide solution, gives a pungent gas B, which turns red litmus blue. The solid, when dissolved in dilute nitric acid and treated with silver nitrate gives a white precipitate of C which is soluble in an ammonia solution.


Sodium hydroxide solution is added first in a small quantity, then in excess to the aqueous salt solutions of copper (II) sulphate, zinc nitrate, lead nitrate, calcium chloride, and iron (III) sulphate. Copy the following table and write the colour of the precipitate in (i) to (v) and the nature of the precipitate (soluble or insoluble) in (vi) to (x).

Aqueous salt solution Colour of precipitate when NaOH is added in a small quantity Nature of precipitate (soluble or insoluble) when NaOH is added in excess
Copper (II) sulphate (i) (vi)
Zinc nitrate (ii) (vii)
Lead nitrate (iii) (viii)
Calcium chloride (iv) (ix)
Iron (III) Sulphate (v) (x)

Distinguish by adding:

Sodium hydroxide solution and ammonium hydroxide solution to Fe(II) salt solution and Fe(III) salt solution.


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