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How will you distinguish between copper and magnesium hydroxide using NH4OН?

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Question

How will you distinguish between copper and magnesium hydroxide using NH4OН?

Distinguish Between
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Solution

You can distinguish between copper hydroxide [Cu(OH)2] and magnesium hydroxide [Mg(OH)₂] by adding excess NH4OH (ammonium hydroxide).

  • Copper hydroxide: Dissolves in excess NH4OH and forms a deep blue solution due to the formation of the tetraamminecopper(II) complex.
  • Magnesium hydroxide: Does not dissolve in NH4OH and remains as a precipitate.

Therefore, the deep blue solution indicates Cu(OH)2, while the unchanged precipitate indicates Mg(OH)2.

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Chapter 4: Analytical Chemistry - Intext Question [Page 86]

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Lakhmir Singh Chemistry [English] Class 10 ICSE
Chapter 4 Analytical Chemistry
Intext Question | Q 8. | Page 86
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