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Question
How does the presence of double bonds in rubber molecules influence their structure and reactivity?
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Solution
Natural rubber is a linear cis-polyisoprene in which the double bonds are present between C2 and C3 of the isoprene units

Because of this cis-configuration, intermolecular interactions between the various strands of isoprene are quite weak. As a result, various strands in natural rubber are arranged randomly. Hence, it shows elasticity.
RELATED QUESTIONS
What is natural rubber?
(A) Cis-1,4-polyisoprene
(B) Neoprene
(C) Trans-1,4-polyisoprene
(D) Butyl rubber
Write names and chemical formulae of monomers used in preparing Buna-S.
Discuss the main purpose of vulcanisation of rubber.
Write the formulae of the raw materials used for preparation of Buna-S
Write the structure of the monomer used in the following polymer:
Buna-S
Which of the following are example of synthetic rubber?
(i) Polychloroprene
(ii) Polyacrylonitrile
(iii) Buna-N
(iv) cis-polyisoprene
Vulcanisation makes rubber:
(i) more elastic
(ii) soluble in inorganic solvent
(iii) crystalline
(iv) more stiff
Match materials given in Column I with the polymers given in Column II.
| Column I | Column II |
| (i) Natural rubber latex | (a) Nylon |
| (ii) Wood laminates | (b) Neoprene |
| (iii) Ropes and fibres | (c) Dacron |
| (iv) Polyester fabric | (d) Melamine formaldehyde resins |
| (v) Synthetic rubber | (e) Urea-formaldehyde resins |
| (vi) Unbreakable crockery | (f) cis-polyisoprene |
Which one of the following monomers gives the polymer neoprene on polymerization?
Which of the following is correct regarding the drawbacks of raw rubber.
Which of the following statement is CORRECT regarding the drawbacks of raw rubber?
In vulcanization of rubber:
Match List I with List II.
| List I | List II |
| (Monomer Unit) | (Polymer) |
| (a) Caprolactum | (i) Natural rubber |
| (b) 2-Chloro-1, 3-butadiene | (ii) Buna-N |
| (c) Isoprene | (iii) Nylon-6 |
| (d) Acrylonitrile | (iv) Neoprene |
Choose the correct answer from the options given below:
Which amongst the following molecules on polymerization produces neoprene?
