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Question
For a chemical reaction \[\ce{2A + B -> 2C + 3D}\], the rate of disappearance of A is 0.10 mol L−1 s−1. Calculate the rate of reaction and the rate of appearance of D.
Numerical
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Solution
The given reaction is \[\ce{2A + B -> 2C + 3D}\] and
the rate of disappearance of A is
\[\ce-{\frac{d[A]}{dt}}\]
= 0.10 mol L−1 s−1
From the stoichiometry
Rate of reaction = \[\ce{\frac{1}{2}-\frac{d[A]}{dt}}\]
= \[\ce{\frac{1}{2} \times 0.10}\]
Rate of reaction = 0.05 mol L−1 s−1
From the balanced equation
Rate of appearance of D = \[\ce{\frac{3}{2}- \frac{d[A]}{dt}}\]
= \[\ce{\frac{3}{2} \times 0.10}\]
Rate of appearance of D = 0.15 mol L−1 s−1
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Chapter 4: Chemical Kinetics - REVIEW EXERCISES [Page 223]
