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Explain the exceptional electronic configuration of Cu. - Chemistry (Theory)

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Question

Explain the exceptional electronic configuration of Cu.

Explain
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Solution

  1. Chromium's electronic configuration is exceptional because it prefers a half-filled 3d subshell for extra stability.
  2. Instead of filling 4s2 and 3d4 (expected), it has 4s1 and 3d5.
  3. This reduces electron repulsion and increases stability by having a half-filled 3d and half-filled 4s subshell.
  4. Similarly, copper has an unusual configuration of 4s1 and 3d10 for a fully filled 3d subshell.
  5. These configurations are more stable than expected due to electron-electron interactions and symmetry.
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Chapter 8: d-and ƒ-Block Elements - SHORT ANSWER TYPE QUESTIONS [Page 496]

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Nootan Chemistry Part 1 and 2 [English] Class 12 ISC
Chapter 8 d-and ƒ-Block Elements
SHORT ANSWER TYPE QUESTIONS | Q 4. ii. | Page 496
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