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Explain the exceptional electronic configuration of Cu. - Chemistry (Theory)

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प्रश्न

Explain the exceptional electronic configuration of Cu.

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उत्तर

  1. Chromium's electronic configuration is exceptional because it prefers a half-filled 3d subshell for extra stability.
  2. Instead of filling 4s2 and 3d4 (expected), it has 4s1 and 3d5.
  3. This reduces electron repulsion and increases stability by having a half-filled 3d and half-filled 4s subshell.
  4. Similarly, copper has an unusual configuration of 4s1 and 3d10 for a fully filled 3d subshell.
  5. These configurations are more stable than expected due to electron-electron interactions and symmetry.
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