English

Explain the Following Terms : Half Life Period of a Reaction (T1/2)

Advertisements
Advertisements

Question

Explain the following terms :

Half life period of a reaction (t1/2)

 

 
Advertisements

Solution

Half life period of a reaction (t1/2)
The half life of a reaction is the time period in which the concentration of a reactant is reduced to one half of its initial concentration.

shaalaa.com
  Is there an error in this question or solution?
2013-2014 (March) Delhi Set 3

Video TutorialsVIEW ALL [1]

RELATED QUESTIONS

The rate constant of a first order reaction increases from 2 × 10−2 to 4 × 10−2 when the temperature changes from 300 K to 310 K. Calculate the energy of activation (Ea).

(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)


The rate of a reaction quadruples when the temperature changes from 293 K to 313 K. Calculate the energy of activation of the reaction assuming that it does not change with temperature.


In the Arrhenius equation for a first order reaction, the values of ‘A’ of ‘Ea’ are 4 × 1013 sec−1 and 98.6 kJ mol1 respectively. At what temperature will its half life period be 10 minutes?

[R = 8.314 J K1 mol1]


During decomposition of an activated complex:

(i) energy is always released

(ii) energy is always absorbed

(iii) energy does not change

(iv) reactants may be formed


Which of the following statements are in accordance with the Arrhenius equation?

(i) Rate of a reaction increases with increase in temperature.

(ii) Rate of a reaction increases with decrease in activation energy.

(iii) Rate constant decreases exponentially with increase in temperature.

(iv) Rate of reaction decreases with decrease in activation energy.


Match the statements given in Column I and Column II

  Column I Column I
(i) Catalyst alters the rate of reaction (a) cannot be fraction or zero
(ii) Molecularity (b) proper orientation is not there always
(iii) Second half life of first order reaction (c) by lowering the activation energy
(iv) `e^((-E_a)/(RT)` (d) is same as the first
(v) Energetically favourable reactions (e) total probability is one are sometimes slow (e) total probability is one
(vi) Area under the Maxwell Boltzman curve is constant (f) refers to the fraction of molecules with energy equal to or greater than activation energy

In respect of the eqn k = \[\ce{Ae^{{-E_a}/{RT}}}\] in chemical kinetics, which one of the following statement is correct?


Explain how and why will the rate of reaction for a given reaction be affected when the temperature at which the reaction was taking place is decreased.


What happens to the rate constant k and activation energy Ea as the temperature of a chemical reaction is increased? Justify.


Which plot of ln k vs `1/T` is consistent with the Arrhenius equation?


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×