Advertisements
Advertisements
Question
Discuss the trend of the following:
Thermal stability of carbonates of Group 2 elements.
Advertisements
Solution
All the alkaline earth metals form carbonates (MCO3). All these carbonates decompose on heating to give CO2 and metal oxide. The thermal stability; of these carbonates increases down the group, i.e., from Be to Ba, BeCO3 < MgCO3 < CaCO3 < SrCO3 < BaCO3
BeCO3 is unstable to the extent that it is stable only in atmosphere of CO2. It however shows reversible decomposition in closed container
\[\ce{BeC03 ⇌ BeO + CO2}\]
Hence, more is the stability of oxide formed, less will be stability of carbonates. Stability of oxides decreases down the group. Since beryllium oxide is high stable, it makes BeCO3 unstable.
APPEARS IN
RELATED QUESTIONS
Which one of the alkaline earth metal carbonates is thermally the most stable?
Assertion: BeSO4 is soluble in water while BaSO4 is not
Reason: Hydration energy decreases down the group from Be to Ba and lattice energy remains almost constant.
Beryllium halides are covalent whereas magnesium halides are ionic why?
Alkaline earth metal (A), belongs to 3rd period reacts with oxygen and nitrogen to form compound (B) and (C) respectively. It undergoes metal displacement reaction with AgNO3 solution to form compound (D). Identify A, B, C and D.
Explain the important common features of Group 2 elements.
Why alkaline earth metals are harder than alkali metals?
The reducing power of a metal depends on various factors. Suggest the factor which makes Li, the strongest reducing agent in aqueous solution.
Some of the Group 2 metal halides are covalent and soluble in organic solvents. Among the following metal halides, the one which is soluble in ethanol is ______.
When sodium is dissolved in liquid ammonia, a solution of deep blue colour is obtained. The colour of the solution is due to ______.
Identify the correct formula of halides of alkaline earth metals from the following.
(i) BaCl2.2H2O
(ii) BaCl2.4H2O
(iii) CaCl2.6H2O
(iv) SrCl2.4H2O
Name an element from Group 2 which forms an amphoteric oxide and a water soluble sulphate.
Why are BeSO4 and MgSO4 readily soluble in water while CaSO4, SrSO4 and BaSO4 are insoluble?
Assertion (A): Beryllium carbonate is kept in the atmosphere of carbon dioxide.
Reason (R): Beryllium carbonate is unstable and decomposes to give beryllium oxide and carbon dioxide.
An element of group 2 forms covalent oxide which is amphoteric in nature and dissolves in water to give an amphoteric hydroxide. Identify the element and write chemical reactions of the hydroxide of the element with an alkali and an acid.
Alkaline earth metals show ______.
Among the following alkaline earth metal halides, one which is covalent and soluble in organic solvents is ______.
