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Correct the following statement: For a strong electrolyte, the plot of equivalent conductance versus concentration of the solution is a straight line. - Chemistry (Theory)

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Question

Correct the following statement:

For a strong electrolyte, the plot of equivalent conductance versus concentration of the solution is a straight line.

Correct and Rewrite
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Solution

Corrected Statement: For a strong electrolyte, the plot of equivalent conductance versus the square root of concentration `(sqrt C​)` is a straight line.

Explanation:
According to Kohlrausch’s law, for strong electrolytes, equivalent conductance decreases linearly with `(sqrt C​)` due to increased interionic interactions at higher concentrations. Hence, a straight-line graph is obtained when Λeq​ is plotted against `(sqrt C​)`​, not directly against C.

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Chapter 3: Electrochemistry - QUESTIONS FROM ISC EXAMINATION PAPERS [Page 213]

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Nootan Chemistry Part 1 and 2 [English] Class 12 ISC
Chapter 3 Electrochemistry
QUESTIONS FROM ISC EXAMINATION PAPERS | Q 4. | Page 213
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