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Question
Correct the following statement:
For a strong electrolyte, the plot of equivalent conductance versus concentration of the solution is a straight line.
Correct and Rewrite
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Solution
Corrected Statement: For a strong electrolyte, the plot of equivalent conductance versus the square root of concentration `(sqrt C)` is a straight line.
Explanation:
According to Kohlrausch’s law, for strong electrolytes, equivalent conductance decreases linearly with `(sqrt C)` due to increased interionic interactions at higher concentrations. Hence, a straight-line graph is obtained when Λeq is plotted against `(sqrt C)`, not directly against C.
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