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Question
Complete the following table which relates to the homologous series of hydrocarbons.
| General formulaе | IUPAC name of the homologous series | Characteristic bond type | IUPAC name of the first member of the series |
| CnH2n−2 | (A) ______ | (B) ______ | (C) ______ |
| CnH2n+1 | (B) ______ | (E) ______ | (F) ______ |
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Solution
| General formulaе | IUPAC name of the homologous series | Characteristic bond type | IUPAC name of the first member of the series |
| CnH2n−2 | (A) Alkyne | (B) Carbon-carbon triple bond | (C) Ethyne |
| CnH2n+1 | (B) Alkyl group | (E) Carbon-carbon single bond | (F) Methyl group |
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| Name | Molecular formula | Condensed structural formula | Number of carbon atom | Number of -CH2- units | Boiling point °C |
| Methane | CH4 | CH4 | 1 | 1 | -162 |
| Ethane | C2H6 | CH3–CH3 | 2 | 2 | -88.5 |
| Propane | C3H8 | CH3–CH2–CH3 | 3 | 3 | -42 |
| Butane | C4H10 | CH3–CH2–CH2–CH3 | ______ | ______ | 0 |
| Pentane | C5H12 | CH3–CH2–CH2–CH2–CH3 | ______ | ______ | 36 |
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| Methanol | CH4O | CH3-OH | 1 | 1 | 63 |
| Ethanol | C2H6O | CH3–CH2-OH | 2 | 2 | 78 |
| Propanol | C3H8O | CH3–CH2–CH2-OH | ______ | ______ | 97 |
| Butanol | C4H10O | CH3–CH2–CH2–CH2–OH | ______ | ______ | 118 |
