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Tamil Nadu Board of Secondary EducationHSC Science Class 12

Compare lanthanoids and actinoids.

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Question

Compare lanthanoids and actinoids.

Distinguish Between
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Solution

Sr. No. Lanthanoids Actinoids
1. The differentiating electron enters in 4f orbital. The differentiating electron enters in 5f orbital.
2. Binding energy of 4f orbitals are higher. Binding energy of 5f orbitals are lower.
3. They show less tendency to form complexes. They show greater tendency to form complexes.
4. Most of the lanthanoids are colourless. Most of the actinoids are coloured.
For example, U3+ (red), U4+ (green), \[\ce{UO^2+_2}\] (yellow)
5. They do not form oxo cations. They do form oxo cations such as \[\ce{UO^2+_2}\] \[\ce{NpO^2+_2}\] etc
6. Besides +3 oxidation states, lanthanoids show +2 and +4 oxidation states in few cases. Besides +3 oxidation states, actinoids show higher oxidation states such as +4, +5, +6 and +7.
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Chapter 4: Transition and Inner Transition Elements - Evaluation [Page 129]

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Samacheer Kalvi Chemistry - Volume 1 and 2 [English] Class 12 TN Board
Chapter 4 Transition and Inner Transition Elements
Evaluation | Q 15. | Page 129

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