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Karnataka Board PUCPUC Science Class 11

Calculate the pH of the following solution: 2 g of TlOH dissolved in water to give 2 litre of solution. - Chemistry

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Question

Calculate the pH of the following solution: 

2 g of TlOH dissolved in water to give 2 litre of solution.

Numerical
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Solution

For 2g of TlOH dissolved in water to give 2 L of solution:

`["TlOH"_("aq")] = 2/2 "g/L"`

`= 2/2 xx 1/221 "M"`

`= 1/221` M

`"TlOH"_("aq") -> "Tl"_("aq")^+ + "OH"_("aq")^-`

`["TlOH"_("aq")^(-)] = ["TlOH"_("aq")] = 1/221 "M"`

`"K"_"M" = ["H"^+ ]["OH"^-]`

`10^(-14) = ["H"^+] (1/221)`

`221 xx 10^(-14) = ["H"^+]`

`=> "pH" = - log ["H"^+] = - log(221 xx 10^(-14))`

`= - log(2.21 xx 10^(-12))`

= 11.65

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