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Question
Calculate the equilibrium constant (Kc) for the formation of NH3 in the following reaction:
\[\ce{N2_{(g)} + 3H2_{(g)} <=> 2NH3_{(g)}}\]
At equilibrium, the concentration of NH3, H2 and N2 are 1.2 × 10−2, 3.0 × 10−2 and 1.5 × 10−2 M respectively.
Numerical
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Solution
\[\ce{N2 + 3H2 <=> 2NH3}\]
Kc = `(["NH"_3]^2)/(["N"_2]["H"_2]^3)`
= `((1.2 xx 10^-2)^2)/((1.5 xx 10^-2)(3 xx 10^-2)^3)`
= `(1.2 xx 1.2 xx 10^-4)/(1.5 xx 10^-2 xx 3 xx 3 xx 3 xx 10^-6)`
= `(1.2 xx 1.2 xx 10^4)/(1.5 xx 9 xx 3)`
= `(1.44 xx 10^4)/(1.5 xx 9 xx 3)`
= 400
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Reversible Reactions and Dynamic Equilibrium - Equilibrium Constant in Terms of Concentration Kc
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