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Karnataka Board PUCPUC Science 2nd PUC Class 12

Assertion: Complexes of MX6 and MX5L type (X and L are unidentate) do not show geometrical isomerism. Reason: Geometrical isomerism is not shown by complexes of coordination number 6.

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Question

Assertion: Complexes of MX6 and MX5L type (X and L are unidentate) do not show geometrical isomerism.

Reason: Geometrical isomerism is not shown by complexes of coordination number 6.

Options

  • Assertion and reason both are true, reason is correct explanation of assertion.

  • Assertion and reason both are true but reason is not the correct explanation of assertion.

  • Assertion is true, reason is false.

  • Assertion is false, reason is true.

MCQ
Assertion and Reasoning
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Solution

Assertion is true, reason is false.

Explanation:

Complexes like MX6 and MX5L have symmetrical ligand arrangements, so they don't exhibit geometrical isomerism. However, coordination number 6 complexes can show geometrical isomerism when they have different ligands arranged in various spatial configurations.

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Chapter 9: Coordination Compounds - Exercises [Page 127]

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NCERT Exemplar Chemistry Exemplar [English] Class 12
Chapter 9 Coordination Compounds
Exercises | Q V. 44. | Page 127

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