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Question
Assertion (A): Zinc displaces copper from copper sulphate solution.
Reason (R): The E of Zn is −0.76V and that of Cu is +0.34V.
Options
If both A and R are true, and R is the correct explanation of A.
If both A and R are true, but R is not the correct explanation of А.
If A is true, but R is false.
If both A and R are false.
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Solution
If both A and R are true, and R is the correct explanation of A.
Explanation:
The assertion is true because zinc is more reactive than copper and spontaneously displaces it from a copper sulphate solution. The reason is also true and provides the correct explanation because zinc has a lower (more negative) standard reduction potential (E° = −0.76 V) than copper (E° = +0.34 V). This difference in electrode potentials confirms that zinc has a stronger tendency to oxidise and act as a reducing agent, allowing it to readily donate electrons to Cu2+ ions.
