English

Answer in brief. What is entropy? Give its units.

Advertisements
Advertisements

Question

Answer in brief.

What is entropy? Give its units.

Short/Brief Note
Advertisements

Solution

  1. Entropy is a measure of molecular disorder or randomness.
  2. An entropy change of a system is equal to the amount of heat transferred (Qrev) to it in a reversible manner divided by the temperature (T) in Kelvin at which the transfer takes place. Thus,
    `triangle "S" = ("Q"_"rev")/"T"`
  3. Units of entropy: J K–1

Note: Entropy or its change ∆S is a state function and depends on the initial and final states of the system and not on the path connecting two states

shaalaa.com
  Is there an error in this question or solution?
Chapter 4: Chemical Thermodynamics - Exercises [Page 87]

APPEARS IN

Balbharati Chemistry [English] Standard 12 Maharashtra State Board
Chapter 4 Chemical Thermodynamics
Exercises | Q 3.2 | Page 87

RELATED QUESTIONS

In which of the following, entropy of the system decreases?


Answer the following in one or two sentences.

If the enthalpy change of a reaction is ∆H how will you calculate the entropy of surroundings?


Answer the following in one or two sentences.

Comment on the spontaneity of reactions for which ∆H is positive and ∆S is negative.


Answer the following question.

Determine whether the following reaction is spontaneous under standard state conditions.

2H2O(l) + O2(g) → 2H2O2(l)

if ΔH° = 196 kJ, ΔS° = –126 J/K, does it have a cross-over temperature?


For a reversible spontaneous change, ∆S is ____________.


Arrange the following in order of increasing entropy.

I. 1.0 mol H2O (298 K, 1 atm)

II. 1.0 mol H2O (270 K, 1 atm)

III. 1.0 mol H2O (400 K, 1 atm)


In how many of the following, ∆S is positive?

i. Melting of ice

ii. Sublimation of iodine

iii. Dissolution of CuSO4 in water

iv. Condensation of water vapour

v. Dissociation of H2 molecule into atoms

vi. Conversion of carbon dioxide gas to dry ice

vii. Vaporization of acetone


Which one of the following has ΔS0 greater than zero?


Heat of combustion of C(s), H2(g) and C2H6(g) are −x1, −x2 and −x3 respectively. Hence heat of formation of C2H6(g) is ____________.


Equilibrium constant for a reaction is 20. What is the value of ∆G0 at 300 K? (R = 8 × 10−3 kJ)


For a reaction to be non-spontaneous at all temperatures, values of ΔH and ΔS respectively are ____________.


Calculate the amount of heat liberated during formation of 2. 7 kg of water if heat of formation of water is - 284.5 kJ mol-1.


For a reaction ΔH = - 30kJ and ΔS = - 45 JK-1, at what temperature reaction changes from spontaneous to non-spontaneous?


For which of the following reaction, ΔH = ΔU?


Relation between ΔH and ΔU for the reaction, \[\ce{2SO_{3(g)} -> 2SO_{2(g)} + O_{2(g)}}\] is _______.


In which of the following reaction the value of Kp will be equal to Kc?


Dinitrogen and dioxygen combined to form nitrous oxide in equilibrium at 850 K. The equilibrium constant for this reaction is 0.56. If the equilibrium concentration of nitrous oxide gas is 3 × 10-3 M and both dinitrogen and dioxygen have the same concentration, then what will be the concentration of dinitrogen gas in M?


Write the correct condition for spontaneity in terms of Gibbs energy.


Identify whether the following pair have larger entropy or not. If yes then Why?

He(g) in a volume of 1 L or He(g) in a volume of 5 L both at 25°C.


Write the relationship between Gibbs energy change for a process and total entropy change of system and surroundings.


ΔH for the reaction is − 110 kJ, and ΔS is + 40 JK−1 at 400 K. The free energy change for the reaction is ______.


Calculate ΔG0 for the reaction

\[\ce{CH_{4(g)} + H_{2(g)}-> C2H_{6(g)}}\]

State whether the reaction is spontaneous or not. (Given: KP = 3.358 × 1017, T = 25° C, R = 8.314 × 10−3 kJK−1 moI−1)


Which of the following is true about the decomposition of ozone?


Change in Gibbs energy for a certain reaction at 300 K is –24 kJ and change in enthalpy is –16 kJ. What is the entropy change of the reaction?


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×