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Question
An element A which is a part of common salt and kept under kerosene reacts with another element B of atomic number 17 to give a product C. When an aqueous solution of product C is electrolysed then a compound D is formed and two gases are liberated.
- What are A and B?
- Identify C and D.
- What will be the action of C on litmus solution? Why?
- State whether element B is a solid, liquid or gas at room temperature.
- Write formula of the compound formed when element B reacts with an element E having atomic number 5.
Very Long Answer
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Solution
- Element A is sodium, and element B is chlorine. Sodium is kept under kerosene because it is highly reactive. The element with atomic number 17 is chlorine. Thus, element A is sodium and element B is chlorine.
- When element A (sodium) reacts with element B (chlorine), it forms a product C, sodium chloride (NaCl).
\[\ce{2Na + Cl2 -> 2NaCl}\]
When an aqueous solution of sodium chloride is electrolysed, compound D, sodium hydroxide (NaOH), is formed along with the evolution of hydrogen and chlorine gases.
\[\ce{2NaCl_{(aq)} + 2H2O_{(l)} ->[Electrolysis] 2NaOH_{(aq)} + H2_{(g)} + Cl2_{(g)}}\] - Compound C is sodium chloride. Sodium chloride has no action on litmus because it is a neutral salt formed from a strong acid (HCl) and a strong base (NaOH), so it does not hydrolyse in water.
- Element B is chlorine. It is in a gaseous state at room temperature.
- The element E with atomic number 5 is boron. When element B, chlorine, reacts with element E, boron, it forms a compound, boron trichloride. The formula of the compound formed is BCl3.
\[\ce{2B + 3Cl2 -> 2BCl3}\]
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