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Question
Account for the following:
Ferric hydroxide sol is positively charged.
Short Answer
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Solution
Ferric hydroxide sol is positively charged because the colloidal particles of Fe(OH)3 preferentially adsorb Fe3+ ions from the solution. These Fe3+ ions are common to the lattice of Fe(OH)3 particles and their adsorption imparts a positive charge to the colloidal particles. This charge prevents aggregation, stabilizing the sol by electrostatic repulsion between similarly charged particles.
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