Advertisements
Advertisements
Question
A gas behaves more closely as an ideal gas at
Options
low pressure and low temperature
low pressure and high temperature
high pressure and low temperature
high pressure and high temperature.
Advertisements
Solution
low pressure and high temperature
At low pressure, the concentration of gas molecules is very low. Hence, the kinetic assumption that the size of the molecules can be neglected compared to the volume of the container applies.
At high temperature, molecules move very fast. So, they tend to collide elastically and forces of interaction between the molecules minimise. This is the required idea condition.
APPEARS IN
RELATED QUESTIONS
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3 s–1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3 s–1. Identify the gas
[Hint: Use Graham’s law of diffusion: R1/R2 = (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
A gas is kept in a rigid cubical container. If a load of 10 kg is put on the top of the container, does the pressure increase?
Explain why cooking is faster in a pressure cooker.
Figure shows graphs of pressure vs density for an ideal gas at two temperatures T1 and T2.
Equal masses of air are sealed in two vessels, one of volume V0 and the other of volume 2V0. If the first vessel is maintained at a temperature 300 K and the other at 600 K, find the ratio of the pressures in the two vessels.
Use R = 8.31 JK-1 mol-1
2 g of hydrogen is sealed in a vessel of volume 0.02 m3 and is maintained at 300 K. Calculate the pressure in the vessel.
Use R=8.3J K-1 mol-1
An air bubble of radius 2.0 mm is formed at the bottom of a 3.3 m deep river. Calculate the radius of the bubble as it comes to the surface. Atmospheric pressure = 1.0 × 105 Pa and density of water = 1000 kg m−3.
A vessel contains 1.60 g of oxygen and 2.80 g of nitrogen. The temperature is maintained at 300 K and the volume of the vessel is 0.166 m3. Find the pressure of the mixture.
Use R = 8.3 J K-1 mol-1
In an adiabatic process on a gas with γ = 1.4, the pressure is increased by 0.5%. The volume decreases by about
A gas is enclosed in a cylindrical can fitted with a piston. The walls of the can and the piston are adiabatic. The initial pressure, volume and temperature of the gas are 100 kPa, 400 cm3 and 300 K, respectively. The ratio of the specific heat capacities of the gas, Cp / Cv = 1.5. Find the pressure and the temperature of the gas if it is (a) suddenly compressed (b) slowly compressed to 100 cm3.
The initial pressure and volume of a given mass of a gas (Cp/Cv = γ) are p0 and V0. The gas can exchange heat with the surrounding. (a) It is slowly compressed to a volume V0/2 and then suddenly compressed to V0/4. Find the final pressure. (b) If the gas is suddenly compressed from the volume V0 to V0/2 and then slowly compressed to V0/4, what will be the final pressure?
A barometer tube is 80 cm long (above the mercury reservoir). It reads 76 cm on a particular day. A small amount of water is introduced in the tube and the reading drops to 75.4 cm. Find the relative humidity in the space above the mercury column if the saturation vapour pressure at the room temperature is 1.0 cm.
The human body has an average temperature of 98°F. Assume that the vapour pressure of the blood in the veins behaves like that of pure water. Find the minimum atmospheric pressure which is necessary to prevent the blood from boiling. Use figure for the vapour pressures.
A faulty barometer contains certain amount of air and saturated water vapour. It reads 74.0 cm when the atmospheric pressure is 76.0 cm of mercury and reads 72.10 cm when the atmospheric pressure is 74.0 cm of mercury. Saturation vapour pressure at the air temperature = 1.0 cm of mercury. Find the length of the barometer tube above the mercury level in the reservoir.
On a winter day, the outside temperature is 0°C and relative humidity 40%. The air from outside comes into a room and is heated to 20°C. What is the relative humidity in the room? The saturation vapour pressure at 0°C is 4.6 mm of mercury and at 20°C it is 18 mm of mercury.
The temperature and relative humidity in a room are 300 K and 20% respectively. The volume of the room is 50 m3. The saturation vapour pressure at 300 K 3.3 kPa. Calculate the mass of the water vapour present in the room.
Use R = 8.3 J K-1 mol-1
A cuboidal container having dimensions 2 m × 1.5 m × 0.5 m holds a mixture of 12 g of He, 36 g of Ar, and 20 g of Ne, If the container is maintained at 300 K, Find the pressure exerted by the mixture (given MHe = 4, MAr = 40, MNe = 20).
Air separated from the atmosphere by a column of mercury of length h = 15 cm is present in a narrow cylindrical two-soldered at one end. When the tube is placed horizontally the air occupies a volume V1 = 240 mm3. When it is set vertically with its open end upwards the volume of the air is V2 = 200 mm3. The atmospheric pressure during the experiment is 7n cm of Hg where n is a single digit number. n will be ______.
