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Question
A copper calorimeter contains 50 g of water at 16°C. When 40 g of water at 36°C is added, the resulting temperature of the mixture is 24°C. Calculate the heat capacity of the calorimeter.
Numerical
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Solution
Let the heat capacity of the copper calorimeter be C' J °C−1.
Heat lost by hot water:
Qlost = 40 × 4.2 × (36 − 24)
= 2016 J
Heat gained by cold water:
$$Q_{\text{gained by water}} = 50 \times 4.2 \times (24 - 16)$$
= 1680 J
Heat gained by the calorimeter:
$$Q_{\text{gained by calorimeter}} = C' \times (24 - 16)$$
= 8C'
From the principle of calorimetry:
1680 + 8C' = 2016
8C' = 336
C' = 42 J °C−1
Therefore, the calorimeter's heat capacity is 42 J °C−1.
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