Advertisements
Advertisements
Question
A colloid is formed by adding \[\ce{FeCl3}\] in excess of hot water. What will happen if excess sodium chloride is added to this colloid?
Advertisements
Solution
\[\ce{FeCl3}\] when added into hot water, it forms hydrated ferric oxide, which is a positively charged sol due to absorption of \[\ce{Fe^{3+}}\] ions. On adding \[\ce{NaCl}\] the negatively charged chloride ions neutralize the positive charge of the solution and coagulation of the sol takes place.
APPEARS IN
RELATED QUESTIONS
Comment on the statement that “colloid is not a substance but a state of substance”.
Distinguish between lyophobic and lyophilic sols.
Write Hardy-Sulze rules.
Explain Electrophoresis diagramatically.
Draw labelled diagram of Bredig’s arc method.
Draw labelled diagram of Soap micelle.
Which type of colloid is formed on the dissolution of soap in water?
Identify the CORRECT statements from the following.
i. The colour of colloidal dispersion depends on size of colloidal particles.
ii. Tyndall effect is used to distinguish between colloidal dispersion and true solution.
iii. Eosin and congo red are examples of negatively charged sols.
The order of coagulating power of following ions in the coagulation of a positive sol is:
i. \[\ce{PO^{3-}_4}\]
ii. \[\ce{SO^{2-}_4}\]
iii. \[\ce{[Fe(CN)6]^{4-}}\]
iv. \[\ce{NO^-_3}\]
Which of the following is NOT true for lyophilic colloids?
Smoke is an example of ____________.
Some colloids are stable by their nature, i.e., gels, alloys, and solid foams. Gelatin and jellies are two common examples of a gel. The solid and liquid phases in a gel are interdispersed with both phases being continuous. In most systems, the major factor influencing the stability is the charge on the colloidal particles. If a particular ion is preferentially adsorbed on the surface of the particles, the particles in suspension will repel each other, thereby preventing the formation of aggregates that are larger than colloidal dimensions. The ion can be either positive or negative depending on the particular colloidal system, i.e., air bubbles accumulate negative ions, sulphur particles have a net negative charge in a sulphur sol, and the particles in a metal hydroxide sol are positively charged. Accumulation of charge on a surface is not an unusual phenomenon-dust is attracted to furniture surfaces by electrostatic forces. When salts are added to lyophobic colloidal systems the colloidal particles begin to form larger aggregates and a sediment forms as they settle. This phenomenon is called flocculation, and the suspension can be referred to as flocculated, or colloidally unstable. If the salt is removed, the suspension can usually be restored to its original state; this process is called deflocculation or peptization. The original and restored colloidal systems are called deflocculated, peptized, or stable sols.
Why does a small amount of salt have such a dramatic effect on the stability of a lyophobic colloidal system? The answer lies in an understanding of the attractive and repulsive forces that exist between colloidal particles. Van der Waals forces are responsible for the attractions, while the repulsive forces are due to the surface charge on the particles. In a stable colloid, the repulsive forces are of greater magnitude than the attractive forces. The magnitude of the electrical repulsion is diminished by addition of ionized salt, which allows the dispersed particles to aggregate and flocculate. River deltas provide an example of this behaviour. A delta is formed at the mouth of a river because the colloidal clay particles are flocculated when the freshwater mixes with the salt water of the ocean.
Gelatin is a _________ colloidal system.
Some colloids are stable by their nature, i.e., gels, alloys, and solid foams. Gelatin and jellies are two common examples of a gel. The solid and liquid phases in a gel are interdispersed with both phases being continuous. In most systems, the major factor influencing the stability is the charge on the colloidal particles. If a particular ion is preferentially adsorbed on the surface of the particles, the particles in suspension will repel each other, thereby preventing the formation of aggregates that are larger than colloidal dimensions. The ion can be either positive or negative depending on the particular colloidal system, i.e., air bubbles accumulate negative ions, sulphur particles have a net negative charge in a sulphur sol, and the particles in a metal hydroxide sol are positively charged. Accumulation of charge on a surface is not an unusual phenomenon-dust is attracted to furniture surfaces by electrostatic forces. When salts are added to lyophobic colloidal systems the colloidal particles begin to form larger aggregates and a sediment forms as they settle. This phenomenon is called flocculation, and the suspension can be referred to as flocculated, or colloidally unstable. If the salt is removed, the suspension can usually be restored to its original state; this process is called deflocculation or peptization. The original and restored colloidal systems are called deflocculated, peptized, or stable sols.
Why does a small amount of salt have such a dramatic effect on the stability of a lyophobic colloidal system? The answer lies in an understanding of the attractive and repulsive forces that exist between colloidal particles. Van der Waals forces are responsible for the attractions, while the repulsive forces are due to the surface charge on the particles. In a stable colloid, the repulsive forces are of greater magnitude than the attractive forces. The magnitude of the electrical repulsion is diminished by addition of ionized salt, which allows the dispersed particles to aggregate and flocculate. River deltas provide an example of this behaviour. A delta is formed at the mouth of a river because the colloidal clay particles are flocculated when the freshwater mixes with the salt water of the ocean.
Settling down of colloidal particles to form a suspension is called ______.
Which of the following process is responsible for the formation of delta at a place where rivers meet the sea?
Why is \[\ce{Fe(OH)3}\] colloid positively charged, when prepared by adding \[\ce{FeCl3}\] to hot water?
Match the items of Column I and Column II.
| Column I | Column II |
| (i) Butter | (a) dispersion of liquid in liquid |
| (ii) Pumice stone | (b) dispersion of solid in liquid |
| (iii) Milk | (c) dispersion of gas in solid |
| (iv) Paints | (d) dispersion of liquid in solid |
Colloids can
Fog is a colloidal solution of ______.
Which of the following is most powerful to coagulate the negative colloid?
Van Arkel's method of purification of metals involves converting the metal to a ______.
