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100 cm3 of a centimolar solution of an acid contain 0.098 g of the acid. Find the molecular mass of the acid. - Chemistry (Theory)

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Question

100 cm3 of a centimolar solution of an acid contain 0.098 g of the acid. Find the molecular mass of the acid.

Numerical
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Solution

Given: Mass % of HNO3 = 69%

Mass of pure HNO3 = 23 g

Density of the solution = 1.41 g/cm3

We are to calculate the volume of solution (in cm3) that contains 23 g of HNO3.

Let volume of the solution be V cm3

Then,

Mass of solution = Density × Volume

= 1.41 × V

Since 69% of the mass is HNO3

Mass of HNO3 = 69% of 1.41 V

Set this equal to 23 g

0.9729 × V = 23

V = `23/0.9729`

V = 23.64 cm3

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