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Write the structural formula and IUPAC names of all possible isomers of the compound with molecular formula C3H8O.
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Calculate the amount of CaCl2 (molar mass = 111 g mol−1) which must be added to 500 g of water to lower its freezing point by 2 K, assuming CaCl2 is completely dissociated. (Kf for water = 1.86 K kg mol−1)
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A first order reaction takes 23.1 minutes for 50% completion. Calculate the time required for 75% completion of this reaction.
(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)
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Calculate the freezing point of solution when 1.9 g of MgCl2 (M = 95 g mol−1) was dissolved in 50 g of water, assuming MgCl2 undergoes complete ionization.
(Kf for water = 1.86 K kg mol−1)
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When 2.56 g of sulphur was dissolved in 100 g of CS2, the freezing point lowered by 0.383 K. Calculate the formula of sulphur (Sx).
(Kf for CS2 = 3.83 K kg mol−1, Atomic mass of sulphur = 32 g mol−1]
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Write the hybridization and magnetic behaviour of the complex [Ni(CO)4].
(At.no. of Ni = 28)
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A first order reaction takes 30 minutes for 50% completion. Calculate the time required for 90% completion of this reaction.
(log 2 = 0.3010)
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Write the hybridization and shape of the following complexe : [CoF6]3–
(Atomic number : Co = 27, Ni = 28)
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Write the hybridization and shape of the following complexe : [Ni(CN)4]2–
(Atomic number : Co = 27, Ni = 28)
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Calculate the freezing point of the solution when 31 g of ethylene glycol (C2H6O2) is dissolved in 500 g of water.
(Kf for water = 1.86 K kg mol–1)
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Draw the structure of: Pyrophosphoric acid
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Write the electronic configuration of the following elements:
Sulphur (Z = 16)
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When primary amine reacts with CHCl3 in alcoholic KOH, the product is _______.
(A) aldehyde
(B) alcohol
(C) cyanide
(D) an isocyanide
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The unit of rate constant for zero order reaction is _______.
(A) t–1
(B) mol dm–3 t–1
(C) mol–1 dm3 t–1
(D) mol–2 dm6 t–1
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Which among the following reactions is an example of a zero order reaction?
a) `H_(2(g)) + I_(2(g)) -> 2HI_(g)`
b) `2H_2O_(2(l)) -> 2H_2O_(l) + O_(2(g))`
c) `C_12H_22O_(11(aq)) + H_2O_(l) -> C_6H_12O_(6(aq)) + C_6H_12O_(6(aq))`
d) `2NH_(3g)` `N(2g) + 3H_(2(g))`
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Define Freezing point.
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3.795 g of sulphur is dissolved in 100g of CS2. This solution boils at 319.81 K. What is the molecular formula of sulphur in solution? The boiling point of CS2 is 319.45 K. (Given that Kb for CS2 = 2.42 K kg mol-1 and atomic mass of S = 32)
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What is the action of following reagents on glucose?
bromine water
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What is the action of following reagents on glucose?
dilute HNO3
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