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Karnataka Board PUCPUC Science 2nd PUC Class 12

PUC Science 2nd PUC Class 12 - Karnataka Board PUC Question Bank Solutions for Chemistry

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Chemistry
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Write the name of the reagent and the equation for the preparation of the following ether by Williamson’s synthesis:

1-Propoxypropane

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Write the name of the reagent and the equation for the preparation of the following ether by Williamson’s synthesis:

Ethoxybenzene

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

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Write the name of the reagent and the equation for the preparation of the following ether by Williamson’s synthesis:

2-Methoxy-2-methylpropane

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

Write the name of the reagent and equation for the preparation of the following ethers by Williamson’s synthesis:

1-Methoxyethane

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

Illustrate with examples the limitations of Williamson synthesis for the preparation of certain types of ethers.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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How is 1-propoxypropane synthesised from propan-1-ol? Write mechanism of this reaction.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Preparation of ethers by acid dehydration of secondary or tertiary alcohols is not a suitable method. Give reason.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Explain the following with an example.

Williamson ether synthesis

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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How will you bring about the following conversion?

Benzene to biphenyl

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
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How the following conversion can be carried out?

Benzene to diphenyl

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
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Explain effects of lanthanoid contraction.

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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What are the consequences of lanthanoid contraction?

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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Draw labelled diagram Dialysis.

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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Name an important alloy which contains some of the lanthanoid metals.

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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Name an important alloy which contains some of the lanthanoid metals. Mention its uses.

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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8 g of glucose, C6H12O6 (Molar Mass = 180 g mol−1) is dissolved in 1 kg of water in a sauce pan. At what temperature will this solution boil? 

(Kb for water = 0.52 K kg mol−1, boiling point of pure water = 373.15 K)

[1] Solutions
Chapter: [1] Solutions
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Calculate the boiling point of solution when 4g of MgSO4 (M= 120 g mol-1) was dissolved in 100g of water, assuming MgSO4 undergoes complete ionization. (Kb for water = 0.52 K kgmol-1)

[1] Solutions
Chapter: [1] Solutions
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Write the structures of A and B in the following reactions

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
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Predict the products of the following reactions:

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
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Illustrate the following reaction giving suitable example in each case: Diazotisation

 

[9] Amines
Chapter: [9] Amines
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