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Karnataka Board PUCPUC Science 2nd PUC Class 12

PUC Science 2nd PUC Class 12 - Karnataka Board PUC Question Bank Solutions for Chemistry

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Chemistry
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Write the hybridization and shape of the following complexe : [CoF6]3–

(Atomic number : Co = 27, Ni = 28)

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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Write the hybridization and shape of the following complexe : [Ni(CN)4]2–

(Atomic number : Co = 27, Ni = 28)

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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What is the role of zinc metal in the extraction of silver ?

[6] General Principles and Processes of Isolation of Elements
Chapter: [6] General Principles and Processes of Isolation of Elements
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Give reasons for the following : Oxygen has less electron gain enthalpy with negative sign than sulphur.

[7] P - Block Elements
Chapter: [7] P - Block Elements
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What role does the molecular interaction play in a solution of alcohol and water?

[1] Solutions
Chapter: [1] Solutions
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How is the sign of ΔmixH related to positive deviations from Raoult’s law?

[1] Solutions
Chapter: [1] Solutions
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Heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid components are 105.2 kPa and 46.8 kPa respectively. What will be the vapour pressure of a mixture of 26.0 g of heptane and 35 g of octane?

[1] Solutions
Chapter: [1] Solutions
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Suggest the most important type of intermolecular attractive interaction in the following pair.

Acetonitrile (CH3CN) and acetone (C3H6O)

[1] Solutions
Chapter: [1] Solutions
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Vapour pressure of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot Ptotal, `P_"chloroform"` and `P_"acetone"` as a function of `chi_"acetone"`. The experimental data observed for different compositions of mixtures is:

`bb(100 xx chi_"acetone")` `bb(P_"acetone"//"mm Hg")` `bb(P_"chloroform"//"mm Hg")`
0 0 632.8
11.8 54.9 548.1
23.4 110.1 469.4
36.0 202.4 359.7
50.8 322.7 257.7
58.2 405.9 193.6
64.5 454.1 161.2
72.1 521.1 120.7

Plot this data also on the same graph paper. Indicate whether it has a positive  or negative deviation from the ideal solution.

[1] Solutions
Chapter: [1] Solutions
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If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would flow through the wire?

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Suggest a list of metals that are extracted electrolytically.

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Consider the reaction:

\[\ce{Cr2O^{2-}_7 + 14H+ + 6e- -> 2Cr^{3+} + 7H2O}\]

What is the quantity of electricity in coulombs needed to reduce 1 mol of  \[\ce{Cr2O^{2-}_7}\]?

[2] Electrochemistry
Chapter: [2] Electrochemistry
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How much charge is required for the following reduction?

1 mol of Al3+ to Al.

[2] Electrochemistry
Chapter: [2] Electrochemistry
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How much charge is required for the following reduction? 

1 mol of Cu2+ to Cu.

[2] Electrochemistry
Chapter: [2] Electrochemistry
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How much charge is required for the following reduction? 

1 mol of \[\ce{MnO^-_4}\] to Mn2+.

[2] Electrochemistry
Chapter: [2] Electrochemistry
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A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current of 5 amperes for 20 minutes. What mass of Ni is deposited at the cathode?

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3 and CuSO4, respectively, are connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver deposited at the cathode of cell B. How long did the current flow? What mass of copper and zinc were deposited?

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Why is the ester hydrolysis slow in the beginning and becomes faster after sometime?

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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What are enzymes? Write in brief the mechanism of enzyme catalysis.

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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Name the processes from which chlorine is obtained as a by-product.

[6] General Principles and Processes of Isolation of Elements
Chapter: [6] General Principles and Processes of Isolation of Elements
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