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Match the items of column I with items of column II.

  Column I Column II
(i) Antifreeze used in car engine (a) Neutral ferric chloride
(ii) Solvent used in perfumes (b) Glycerol
(iii) Starting material for picric acid (c) Methanol
(iv) Wood spirit (d) Phenol
(v) Reagent used for detection of phenolic group (e) Ethleneglycol
(vi) By product of soap industry used in cosmetics (f) Ethanol
[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

Match the items of column I with items of column II.

  Column I Column II
(i) Methanol (a) Conversion of phenol to o-hydroxysalicylic acid
(ii) Kolbe’s reaction (b) Ethyl alcohol
(iii) Williamson’s synthesis (c) Conversion of phenol to salicylaldehyde
(iv) Conversion of 2° alcohol to ketone (d) Wood spirit
(v) Reimer-Tiemann reaction (e) Heated copper at 573 K
(vi) Fermentation (f) Reaction of alkyl halide with sodium alkoxide
[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

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Assertion: Ethanol is a weaker acid than phenol.

Reason: Sodium ethoxide may be prepared by the reaction of ethanol with aqueous \[\ce{NaOH}\].

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

The correct order of increasing acidic strength is ______.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

In the nitration of benzene using a mixture of conc. \[\ce{H2SO4}\] and conc. \[\ce{HNO3}\], the species which initiates the reaction is ______.

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

What is the role of \[\ce{HNO3}\] in the nitrating mixture used for nitration of benzene?

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

A solution contains 1 g mol. each of p-toluene diazonium chloride and p-nitrophenyl diazonium chloride. To this 1 g mol. of alkaline solution of phenol is added. Predict the major product. Explain your answer.

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Assertion: N, N-Diethylbenzene sulphonamide is insoluble in alkali.

Reason: Sulphonyl group attached to nitrogen atom is strong electron-withdrawing group.

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Which of the following acids is a vitamin?

[10] Biomolecules
Chapter: [10] Biomolecules
Concept: undefined >> undefined

Each polypeptide in a protein has amino acids linked with each other in a specific sequence. This sequence of amino acids is said to be ______.

[10] Biomolecules
Chapter: [10] Biomolecules
Concept: undefined >> undefined

Lysine, \[\begin{array}{cc}
\ce{H2N - (CH2)4 - CH - COOH}\\
\phantom{.....}|\\
\phantom{........}\ce{NH2}
\end{array}\] is:

(i) α-Amino acid

(ii) Basic amino acid

(iii) Amino acid synthesised in body

(iv) β-Amino acid

[10] Biomolecules
Chapter: [10] Biomolecules
Concept: undefined >> undefined

Amino acids can be classified as α–, β–, γ–, δ– and so on depending upon the relative position of amino group with respect to carboxyl group. Which type of amino acids form polypetide chain in proteins?

[10] Biomolecules
Chapter: [10] Biomolecules
Concept: undefined >> undefined

Amino acids behave like salts rather than simple amines or carboxylic acids. Explain.

[10] Biomolecules
Chapter: [10] Biomolecules
Concept: undefined >> undefined

Describe the term D- and L- configuration used for amino acids with examples.

[10] Biomolecules
Chapter: [10] Biomolecules
Concept: undefined >> undefined

Which of the following polymer is biodegradable?

[15] Polymers
Chapter: [15] Polymers
Concept: undefined >> undefined

Which of the following polymer can be formed by using the following monomer unit?

[15] Polymers
Chapter: [15] Polymers
Concept: undefined >> undefined

Which of the following monomers form biodegradable polymers?

(i) 3-hydroxybutanoic acid + 3-hydroxypentanoic acid

(ii) Glycine + amino caproic acid

(iii) Ethylene glycol + phthalic acid

(iv) Caprolactum

[15] Polymers
Chapter: [15] Polymers
Concept: undefined >> undefined

Convert the following: 

Propanenitrile to ethanol.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

[Ni(H2O)6]2+ (aq) is green in colour whereas [Ni(H2O)4 (en)]2+ (aq)is blue in colour, give reason in support of your answer.

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined

In a coordination entity, the electronic configuration of the central metal ion is t2g3 eg

Draw the crystal field splitting diagram for the above complex.

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined
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