Science (English Medium) इयत्ता १२ - CBSE Question Bank Solutions

Name the following halide according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3C(C2H5)2CH2Br}\]

Define “zero order reaction”.

In a first order reaction x → y, 40% of the given sample of compound remains unreacted in 45 minutes. Calculate rate constant of the reaction.

The major binding force in diamond is_______________ .

(a) Covalent bond                                                  

(b)  Ionic bond

(c) Metallic bond                                                   

(d)  Co-ordinate covalent bond

What is the covalency of nitrogen in N₂O₅?

A reaction is second order in A and first order in B.

(i) Write the differential rate equation.

(ii) How is the rate affected on increasing the concentration of A three times?

(iii) How is the rate affected when the concentrations of both A and B are doubled?

Give an example each of a molecular solid and an ionic solid.

For a reaction: 

Rate = k

(i) Write the order and molecularity of this reaction.

(ii) Write the unit of k.

For the first order thermal decomposition reaction, the following data were obtained:

Time / sec               Totalpressure / atm

0                              0.30

300                          0.50

Calculate the rate constant

(Given: log 2 = 0.301, log3 = 0.4771, log 4 = 0.6021)

Write two factors that affect the rate of reaction.

For a reaction A + B ⟶ P, the rate is given by

Rate = k [A] [B]²

How is the rate of reaction affected if the concentration of B is doubled?

For a reaction A + B ⟶ P, the rate is given by

Rate = k [A] [B]²

What is the overall order of reaction if A is present in large excess?

For a reaction : 

(i) Write the order and molecularity of this reaction.

(ii) Write the unit of k.

For the hydrolysis of methyl acetate in aqueous solution, the following results were obtained :

(i) Show that it follows pseudo first order reaction, as the concentration of water remains constant.

(ii) Calculate the average rate of reaction between the time interval 30 to 60 seconds.

(Given log 2 = 0.3010, log 4 = 0.6021)

Write the IUPAC name of the given compound:

Write the names and structures of the monomers of the following polymers: Polyvinyl chloride

For a chemical reaction R → P, the variation in the concentration (R) vs. time (t) plot is given as:

(i) Predict the order of the reaction.

(ii) What is the slope of the curve?

(iii) Write the unit of rate constant for this reaction.

Write the name of monomers used for getting the following polymers : Bakelite

The following data were obtained during the first order thermal decomposition of SO₂Cl₂ at a constant volume :

SO₂Cl₂ (g) → SO₂ (g) + Cl₂ (g)

Calculate the rate constant.

(Given : log 4 = 0.6021, log 2 = 0.3010)

Write the name of the monomer used for getting the following polymer:

Teflon