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Which of the following is not correct?
Concept: Classification of Crystalline Solids
In which of the following solvents, the \[\ce{C4H8NH3+X–}\] is soluble?
Concept: Solubility >> Solubility of a Gas in a Liquid
What is the effect of temperature on the solubility of glucose in water?
Concept: Solubility >> Solubility of a Solid in a Liquid
Ibrahim collected 10 mL each of fresh water and ocean water. He observed that one sample labeled “P” froze at 0° C while the other “Q” at -1.3° C. Ibrahim forgot which of the two, “P” or “Q” was ocean water. Help him identify which container contains ocean water, giving rationalization for your answer.
Concept: Colligative Properties and Determination of Molar Mass >> Depression of Freezing Point
Calculate Van't Hoff factor for an aqueous solution of K3 [Fe(CN)6] if the degree of dissociation (α) is 0.852. What will be boiling point of this solution if its concentration is 1 molal? (Kb = 0.52 K kg/mol)
Concept: Abnormal Molar Masses
What type of deviation from Roult’s Law is expected when phenol and aniline are mixed with each other? What change in the net volume of the mixture is expected? Graphically represent the deviation.
Concept: Ideal and Non-ideal Solutions
The vapour pressure of pure water at a certain temperature is 23.80 mm Hg. If 1 mole of a non-volatile non-electrolytic solute is dissolved in 100g water, Calculate the resultant vapour pressure of the solution.
Concept: Colligative Properties and Determination of Molar Mass >> Relative Lowering of Vapour Pressure
A 5% solution of \[\ce{Na2SO4.10H2O}\] (MW = 3 22) is isotonic with 2% solution of non- electrolytic, non volatile substance X. Find out the molecular weight of X.
Concept: Expressing Concentration of Solutions
Write the two applications of Henry’s law.
Concept: Solubility >> Solubility of a Gas in a Liquid
Define “Molar conductivity”.
Concept: Conductance of Electrolytic Solutions >> Variation of Conductivity and Molar Conductivity with Concentration
How much electricity in terms of Faraday is required to produce 20 g of Ca from molten CaCl2?
(Given: Molar mass of Calcium is 40 g mol−1.)
Concept: Electrolytic Cells and Electrolysis - Introduction
The conductivity of 0.20 M solution of KCl at 298 K is 0.025 S cm−1. Calculate its molar conductivity.
Concept: Conductance of Electrolytic Solutions >> Variation of Conductivity and Molar Conductivity with Concentration
State Kohlrausch Law.
Concept: Conductance of Electrolytic Solutions >> Variation of Conductivity and Molar Conductivity with Concentration
Using the E° values of A and B, predict which is better for coating the surface of iron [E°(Fe+2/Fe) = -0.44V] to prevent corrosion and why?
Given: E° (A+2/A)=-2.37 V: E°(B+2/B)= -0.14V
Concept: Electrolytic Cells and Electrolysis - Introduction
The conductivity of 0.001 mol L-1 solution of CH3COOH is 3.905× 10-5 S cm-1. Calculate its molar conductivity and degree of dissociation (α) Given λ°(H+)= 349.6 S cm2 mol-1 and λ°(CH3COO)= 40.9S cm2mol-1.
Concept: Conductance of Electrolytic Solutions >> Variation of Conductivity and Molar Conductivity with Concentration
Define electrochemical cell
Concept: Batteries >> Primary Batteries
Following reactions occur at cathode during the electrolysis of aqueous sodium chloride solution:
Na+(aq) + e− ⟶ Na (s) E0 = 2.71 V
H+(aq) + e− ⟶ `1/2` H2 (g) E0 = 0.00 V
On the basis of their standard reduction electrode potential (E0) values, which reaction is feasible at the cathode and why?
Concept: Electrolytic Cells and Electrolysis - Introduction
Why does the cell potential of mercury cell remain constant throughout its life?
Concept: Batteries >> Primary Batteries
Define the following terms: Molar conductivity (⋀m)
Concept: Conductance of Electrolytic Solutions >> Variation of Conductivity and Molar Conductivity with Concentration
Define the following terms: Secondary batteries
Concept: Batteries >> Primary Batteries
