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Revision: Organic Chemistry >> Organic Compounds Chemistry (English Medium) ICSE Class 10 CISCE

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Definitions [25]

Definition: Inorganic Chemistry

The branch of chemistry that deals with compounds obtained from non-living sources or minerals, such as common salt, blue vitriol, and nitrates.

Definition: Organic Chemistry

The branch of chemistry that deals with compounds originally derived from living organisms, such as sugar, starch, proteins, and acetic acid.

Define a functional group.

An atom or a group of atoms attached to an alkyl group, which takes part in most of the chemical reactions, is called a functional group or functional radical.

Definition: Organic Compounds

Organic compounds are the compounds of carbon.

Define of chain isomerism.

When two or more compounds have a similar molecular formula but are different in the arrangement of carbon atoms in straight or branched chains, the compounds are referred to as chain isomers.

Define isomerism.

Compounds having the same molecular formula but different structural formulas are called isomers and the phenomenon is called isomerism.

Definition: Tetravalency of Carbon

The characteristic of the carbon atom, by virtue of which it forms four covalent bonds, is called the tetravalency of carbon.

Define the following:

Adsorption

Adsorption is the property due to which a substance absorbs gases, liquids and solids on its surface.

Define the following:

Carbonization

The process of the slow conversion of vegetable matter into carbon-rich substances is called carbonization.

Define catenation.

Carbon possesses a unique property of combining with other carbon atoms to form long chains. This property is called catenation. The chains can be straight, branched or closed.

The self-linking property of atoms of an element to form very long straight or branched chains and cyclic rings is known as catenation. This property is shown by carbon whose small size and tetravalency helps it to form large structures by self-linking.

Definition: Catenation

The property of self-linking of atoms of an element through covalent bonds in order to form straight chains, branched chains and cyclic chains of different sizes is known as catenation.

Definition: Alkanes

Saturated hydrocarbons (containing a single bond) are called ‘Alkanes’.

Definition: Hydrocarbons

Hydrocarbons are compounds that 9re made up only of carbon and hydrogen atoms.

OR

The compounds which contain carbon and hydrogen as the only two elements are called hydrocarbons.

Definition: Saturated Hydrocarbons

Saturated hydrocarbons are hydrocarbons in which the valencies of all atoms are satisfied by single bonds.

Definition: Alkenes

The unsaturated hydrocarbons containing a carbon-carbon double bond are called ‘Alkenes’.

Definition: Alkynes

The unsaturated hydrocarbons whose structures contain a carbon-carbon triple bond are called ‘Alkynes’.

Definition: Unsaturated Compounds

The hydrocarbons that have double or triple covalent bonds between two adjacent carbon atoms are called unsaturated hydrocarbons.

OR

The carbon compounds having a double bond or triple bond between two carbon atoms are called unsaturated compounds. Ethene and ethyne are unsaturated hydrocarbons.

Definition: Carbocyclic Compounds

Cyclic compounds are organic compounds in which the carbon atoms are arranged in a ring or cyclic structure. When these rings contain only carbon atoms, they are called carbocyclic compounds, and their properties are similar to open-chain hydrocarbons.

Definition: Structural Formula

The formula that shows how atoms of different elements are linked together in a molecule is known as a structural formula.

Definition: Carbon Skeleton

A structure that shows only the linking of carbon atoms in a molecule is called the carbon skeleton.

Definition: Functional Group

The functional group is defined as an atom or group of atoms joined in a specific manner which is responsible for the characteristic chemical properties of the organic compounds.

Definition: Homologous Series

The same functional group substitutes for hydrogen in a carbon chain is called a homologous series.

OR

A homologous series is a group of organic compounds having  similar structure and similar chemical properties in which the successive compounds differ by a CH2 group.

OR

The series of compounds formed by joining the same functional group in the place of a particular hydrogen atom on the chains having sequentially increasing length is called homologous series.

Define Homologous series.

A series of compounds with similar chemical properties, in which members differ from one another by an additional CH2 group, is called a homologous series.

Definition: Nomenclature

Nomenclature is the system of assignment of names to organic compounds.

Definition: Isomers

Compounds having the same molecular formula but different structural formula are known as Isomers and the phenomenon is known as Isomerism. (iso = same, meros = parts).

Formulae [1]

Give the general formula of carboxylic acids.

CnH2n+1COOH (or RCOOH)

Key Points

Key Points: Organic Compounds
  • Specification: Organic chemistry studies carbon compounds (excluding CO₂, carbonates, etc.).
  • Sources: Found in plants, animals, coal, petroleum, wood, and by fermentation.
  • Lab Synthesis: Many organic compounds are made in labs today.
  • Daily Use: Found in soaps, clothes, fuels, medicines, food, etc.
  • Importance: Organic compounds are used in almost every part of life.
Key Points: Carbon: A Versatile Element
  • Carbon forms many compounds, from simple ones like methane to complex ones like DNA, due to its bonding versatility.
  • Catenation allows carbon to form long chains or rings by bonding with itself.
  • Carbon forms single, double, and triple covalent bonds, leading to saturated and unsaturated compounds.
  • Being tetravalent, carbon forms four strong covalent bonds with elements like H, O, N, and Cl.
  • Isomerism increases the number of carbon compounds by allowing different structures with the same molecular formula.
 
Key Points: Types of Organic Compounds
Types of Compound Identified by the Presence of Example
1. Hydrocarbon    
(a) Alkane –C–C– bond Ethane H₃C–CH₃
(b) Alkene –C=C– bond Ethene H₂C=CH₂
(c) Alkyne –C≡C– bond Ethyne HC≡CH
2. Alcohol –OH group Methanol CH₃OH
3. Aldehyde –CHO group Ethanal CH₃CHO
4. Ketone >C=O Propanone CH₃COCH₃
5. Carboxylic Acid –COOH group Ethanoic acid CH₃COOH
6. Ether C–O–C group Dimethyl ether H₃C–O–CH₃
7. Halide –X (F, Cl, Br, I) Chloroethane C₂H₅Cl
Key Points: Hydrocarbons
  • Hydrocarbons contain only carbon and hydrogen atoms and are the basic type of organic compounds.
  • Saturated hydrocarbons have single bonds (e.g. methane, ethane, propane).
  • Unsaturated hydrocarbons have double or triple bonds (e.g. ethene, ethyne).
  • To draw structures, join the carbon atoms first, then add hydrogen atoms to complete 4 bonds per carbon.
  • Ethene has a double bond, and ethyne has a triple bond between carbon atoms.
Key Points: Homologous Series
  • A homologous series is a group of compounds with the same functional group and similar chemical properties.
  • Successive members differ by one CH₂ (methylene) unit, increasing the molecular mass by 14 u.
  • All members of a homologous series follow the same general molecular formula (e.g., alkanes CnH2n+2).
  • Physical properties such as boiling and melting points show a gradual change with increasing molecular mass.
  • Knowing the properties of a few members helps predict the properties of other members in the series.
Key points: Nomenclature of Carbon Compounds
  • The IUPAC system provides a unique, systematic way to name carbon compounds based on structure, replacing confusing common names.
  • An IUPAC name has three parts: prefix, parent, and suffix, reflecting the carbon chain and functional group.
  • The parent name is based on the longest carbon chain, and its ending changes to –ane, –ene, or –yne depending on the number of bonds.
  • Functional groups are shown as prefixes or suffixes, and the chain is numbered to give them the lowest possible number.
  • If the suffix begins with a vowel, the final ‘e’ in the parent alkane name is dropped (e.g., propane → propanone).
Key Points: Rules of Nomenclature
  • Longest Chain: Choose the longest continuous carbon chain as the parent chain.
  • Numbering: Number the chain so that branches or functional groups get the lowest possible numbers.
  • Substituents: Name and position of alkyl groups are placed before the parent name (e.g., 3-methylpentane).
  • Multiple Groups: Use prefixes like di-, tri-, etc., for repeated groups (e.g., 2,2-dimethylbutane).
  • Alphabetical Order: Different substituents are listed alphabetically (e.g., 2-bromo-4-chlorohexane).
Key Points: Types of Structural Isomerism
  • Chain Isomerism: Same formula, different carbon chain structures (e.g., straight or branched).
  • Position Isomerism: Same formula, functional group at different positions.
  • Functional Isomerism: Same formula, different functional groups (e.g., alcohol vs ether).
  • Metamerism (not in syllabus): Different alkyl groups on both sides of a functional group.
  • More Carbons = More Isomers: The number of isomers increases with the number of carbon atoms.

Important Questions [18]

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