- Davisson and Germer tested de Broglie’s idea by firing electrons at a nickel crystal.
- Electrons were accelerated through a known voltage and allowed to scatter from the crystal.
- The scattered electrons formed a diffraction pattern, showing wave behaviour.
- The measured wavelength matched the value calculated from de Broglie’s formula.
- The experiment demonstrated that electrons exhibit wave-like behaviour and confirmed wave–particle duality.
Definitions [24]
Define threshold frequency.
The minimum frequency of incident radiation required to start photoemission in any photosensitive material is known as the threshold frequency.
Define photoelectric effect.
The phenomenon of emission of electrons from a metal surface when radiation of appropriate frequency is incident on it is known as the photoelectric effect.
Define the work function of the metal.
The minimum amount of energy required to be provided to an electron to pull it out of the metal from the surface is called the work function of the metal.
Definition: Work Function
The minimum energy required to remove an electron from the surface of a metal is called the work function of the metal.
It is denoted by ϕ0.
Definition: Electromagnetic Radiation
Electromagnetic radiation consists of mutually perpendicular oscillating electric and magnetic fields, both perpendicular to the direction of propagation of the wave.
Definition: Photoelectric Effect
The phenomenon of emission of electrons from a metal surface when radiation of appropriate frequency is incident on it is called the photoelectric effect.
Definition: Photoelectrons
Electrons emitted from a metal surface due to incident light are called photoelectrons.
Definition: Photosensitive Surface
A surface that emits electrons when illuminated with suitable radiation is called a photosensitive surface.
Definition: Accelerating Potential
When the anode is at positive potential with respect to the cathode, it accelerates the emitted electrons. This potential is called accelerating potential.
Definition: Retarding Potential
When the anode is at negative potential with respect to the cathode, it opposes the motion of electrons. This is called retarding potential.
Definition: Stopping Potential
The minimum negative potential applied to the collector to reduce the photocurrent to zero is called the stopping potential (cut-off potential).
Definition: Einstein’s Relation
The relation E = hν, which connects the energy of a photon with its frequency, is called Einstein’s relation.
Definition: de Broglie Wavelength
The wavelength associated with a moving material particle is called the de Broglie wavelength.
Definition: Thermionic Emission
The emission of electrons from a metal surface by heating it to high temperature is called thermionic emission.
Definition: Field Emission
The emission of electrons from a metal surface by applying a strong electric field is called field emission.
Definition: Electron Microscope
A microscope that uses accelerated electron beams instead of visible light to obtain high-resolution images is called an electron microscope.
Definition: Photocell
A device that uses the photoelectric effect to convert light energy into electrical energy is called a photocell.
Definition: Photon
The quantum (bundle) of electromagnetic radiation having energy E = hν is called a photon.
Definition: Wave–particle Duality of Electromagnetic Radiation
The property of electromagnetic radiation to exhibit both wave nature and particle nature is called wave–particle duality of electromagnetic radiation.
Definition: Compton Shift
The change in wavelength of X-rays after scattering from electrons is called the Compton shift.
Definition: Threshold Frequency
The minimum frequency of incident radiation required to eject electrons from a metal surface (ν0 = ϕ0/h) is called the threshold frequency.
Definition: Einstein’s Photoelectric Equation
The maximum kinetic energy of emitted photoelectrons given by KEmax = hν − ϕ0 is called Einstein’s photoelectric equation.
Definition: de Broglie Hypothesis
The hypothesis that matter, like radiation, exhibits both wave and particle nature is called the de Broglie hypothesis.
Definition: Matter Waves
The waves associated with moving material particles are called matter waves.
Formulae [8]
Formula: de Broglie Relation
λ = \[\frac {h}{p}\]
\[
\lambda = \frac{h}{mv}
\]
Formula: Value of Charge of Electron
\[
e = 1.602 \times 10^{-19}\,\text{C}
\]
Formula: Electron Volt (eV)
\[
1\,\text{eV} = 1.602 \times 10^{-19}\,\text{J}
\]
Formula: Specific Charge of Electron
\[
\frac{e}{m} = 1.76 \times 10^{11}\,\text{C/kg}
\]
Formula: Threshold Frequency
\[
\nu_0 = \frac{\phi_0}{h}
\]
Formula: Einstein’s Photoelectric Equation
\[
K_{\text{max}} = eV_0
\]
or
\[
K_{\text{max}} = h\nu - \phi_0
\]
Linear Form:
\[
V_0 = \frac{h}{e}\nu - \frac{\phi_0}{e}
\]
Formula: Photon Momentum
\[
p = \frac{h\nu}{c} = \frac{h}{\lambda}
\]
Formula: Compton Shift
\[\Delta\lambda=\lambda^{\prime}-\lambda=\frac{h}{m_ec}(1-\cos\theta)\]
Key Points
Key Points: Failure of Wove Theory
- Wave theory could not explain the instant emission of electrons; it predicted a time delay.
- It said higher intensity should give higher kinetic energy, but actually, kinetic energy depends on frequency, not intensity.
- Wave theory predicts emission at any frequency when intensity is high, but emission occurs only when the frequency is above the threshold frequency (ν₀).
- Even very low intensity light causes immediate emission, which contradicts wave theory.
- Hence, the photoelectric effect supported the particle (quantum) nature of light rather than the wave theory.
Key Points: Photoelectric Effect – Key Observations
- Electrons are emitted only if the light frequency is greater than a minimum value, the threshold frequency (ν₀), which differs for different metals.
- Emission of electrons is instantaneous; there is no time delay between light falling and electrons coming out.
- At a fixed frequency, photocurrent increases with increasing light intensity.
- Photocurrent increases with accelerating potential and then becomes constant; this maximum value is called the saturation current.
- Saturation current depends on light intensity, not on its frequency (if ν > ν₀).
- The maximum kinetic energy of emitted electrons depends only on the frequency of light, not on its intensity.
- Stopping potential is the minimum negative potential needed to stop the photocurrent; it depends on frequency, not on intensity.
Key Points: Einstein's Postulates
- Einstein extended Planck’s idea and proposed that light behaves as particles called photons, each carrying energy hνh\nuhν.
- A photon gives all its energy to a single electron; emission occurs only if this energy is equal to or greater than the work function of the metal.
- Photoelectric emission is instantaneous because energy transfer from photon to electron occurs in a single interaction.
- The intensity of light controls the number of emitted electrons (photocurrent), while the frequency controls the maximum kinetic energy of the electrons.
- Einstein’s photon theory successfully explained threshold frequency, stopping potential, saturation current, and all experimental observations of the photoelectric effect.
Key Points: Davisson and Germer Experiment
Key Points: Wave-Particle Duality of Matter
Important Questions [14]
- In a photoelectric experiment, the stopping potential is 1.5V. What is the maximum kinetic energy of a photoelectron?
- With the help of a circuit diagram describing an experiment to study the photoelectric effect.
- With the help of a circuit diagram describe the experiment to study the characteristics of the photoelectric effect. Hence discuss any 2 characteristics of the photoelectric effect.
- Is it always necessary to use red light to get a photoelectric effect?
- If the maximum kinetic energy of emitted electrons in the photoelectric effect is 2eV, the stopping potential will be ______.
- If the frequency of incident light falling on a photosensitive material is doubled, then the kinetic energy of the emitted photoelectron will be ______.
- What is the photoelectric effect?
- Define photoelectric effect.
- State Einstein photoelectric equation.
- An electron, a proton, an α-particle, and a hydrogen atom are moving with the same kinetic energy. The associated de Broglie wavelength will be longest for ______.
- Explain de-Broglie wavelength.
- The de Broglie wavelengths associated with an electron and a proton are same. What will be the ratio of (i) their momenta (ii) their kinetic energies?
- Obtain an expression for de-Broglie wavelength of wave associated with material particles. The photoelectric work function for metal is 4.2 eV. Find the threshold wavelength.
- An electron is accelerated through a potential difference of 100 volts. Calculate de-Broglie wavelength in nm.
