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Revision: Structure of Atoms and Nuclei Physics HSC Science (General) 12th Standard Board Exam Maharashtra State Board

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Definitions [48]

Define the term mass number.

The total number of neutrons and protons in the nucleus is called the mass number of the element and is denoted by A.

Define the term atomic number.

The number of protons in the nucleus is known as the atomic number of the element and is denoted by Z.

Definition: Atomic Number

The atomic number of an atom is equal to the number of protons in its nucleus (which is same as the number of electrons in a neutral atom).

Definition: Mass Number

The mass number of an atom is equal to the total number of nucleons (i.e., the sum of the number of protons and the number of neutrons) in its nucleus.

Define the term Nucleons.

The nucleus is made up of protons and neutrons, with protons having a positive charge and neutrons being neutral. Nucleons are made up of protons and neutrons.

Definition: Isotopes

The atoms of the same element, having same atomic number Z, but different mass number A, are called isotopes.

OR

Atoms having the same atomic number (Z) but different mass numbers (A).

Definition: Nuclear Energy

The energy released due to loss in mass during the processes of nuclear fission and fusion is called nuclear (or atomic) energy.

OR

The energy released when nuclei undergo a nuclear reaction (change in structure, forming new nuclei) is called nuclear energy.

Define binding energy per nucleon.

Binding energy per nucleon is the least amount of energy required to liberate all of the nucleons from the nucleus.

As a result, the binding energy per nucleon is
`E_B/A`

Define half-life period.

The half-life of a reaction is the time it takes for a reactant’s concentration to decrease to half of its initial value.

Define one Becquerel.

One Becquerel (Bq) is defined as the activity of a quantity of radioactive samples in which one nucleus decays per second. It is the SI unit of the activity.

Definition: Electron

The negatively charged particles discovered by J. J. Thomson are called electrons.

Definition: Thomson’s Atomic Model

The atomic model proposed by J. J. Thomson in which an atom is considered as a uniformly positively charged sphere with electrons embedded in it is called Thomson’s atomic model. Thomson’s atomic model is also called the plum-pudding model.

Definition: Electrically Neutral Atom

An atom having equal total positive and negative charges and therefore having no net charge is called an electrically neutral atom.

Definition: Spectra Series

The groups of spectral lines arranged according to a pattern are called spectral series (such as Lyman series, Balmer series, Paschen series, etc.).

Definition: Stable Orbits

The circular paths in which electrons revolve around the nucleus without emitting radiation are called stable orbits (stationary states).

Definition: Bohr’s Quantization Condition

The condition that the angular momentum of an electron in a stable orbit is an integral multiple of \[\frac {h}{2π}\] is called Bohr’s quantization condition.

Definition: Electronic Transition

The process in which an electron moves from one orbit to another with emission or absorption of a photon is called an electronic transition.

Definition: Principal Quantum Number

The positive integer nnn that determines the orbit of an electron is called the principal quantum number.

Definition: Line Spectrum

The spectrum obtained when a hot gas emits radiation at only certain specific wavelengths is called a line spectrum.

Definition: Emission Lines

The bright lines seen in the spectrum due to emission of radiation at specific wavelengths are called emission lines.

Definition: Bohr Radius

The radius of the first orbit of the hydrogen atom (n = 1) is called the Bohr radius.

Definition: Ground State

The lowest energy state of an atom (n = 1) is called the ground state.

Definition: Excitation Energy

The higher energy states (n > 1) are called excited states. The minimum energy required to raise an electron from the ground state to a higher energy state is called the excitation energy.

Definition: Rydberg Constant

The constant appearing in the spectral formula of hydrogen is called the Rydberg constant.

RH = \[\frac{m_{\mathrm{e}}e^{4}}{8c\varepsilon_{0}h^{3}}=1.097\times10^{7}\mathrm{m}^{-1}\]

Definition: Ionization Energy

The ionisation energy of an atom is the minimum amount of energy required to be given to an electron in the ground state of that atom to set the electron free.

Definition: Nucleons

Protons and neutrons together are called nucleons.

Definition: Isobars

Atoms having the same mass number (A) but different atomic numbers (Z).

Definition: Isotones

Atoms having the same number of neutrons (N) but different atomic numbers (Z).

Definition: Beta Plus (β⁺) Decay

The emission of a positron due to conversion of a proton into a neutron inside the nucleus is called beta plus (β⁺) decay.

\[_Z^AX\to_{Z-1}^AY+e^++\mathrm{neutrino}\]

Definition: Beta Minus (β⁻) Decay

The emission of an electron due to the conversion of a neutron into a proton inside the nucleus is called beta minus (β⁻) decay.

\[{}_Z^AX\to{}_{Z+1}^AY+e^-+\text{antineutrino}\]

Q = [mX mY me]c2

Definition: Gamma Decay

The emission of high-energy photons from an excited nucleus without a change in mass number or atomic number is called gamma decay.

\[_Z^AX^*\to_Z^AX+\gamma\]

Definition: Q-value of the Decay

The difference between the mass of the parent atom and the total mass of the decay products, expressed in energy terms, is called the Q-value of the decay.

Definition: Alpha Decay

The emission of an alpha particle (helium nucleus) from a heavy nucleus is called alpha decay.

\[{}_Z^AX\to{}_{Z-2}^{A-4}Y+{}_2^4He\]

Q = [mX mYmHe]c2

Definition: Mass Defect

The difference between the total mass of individual nucleons and the actual mass of the nucleus.

ΔM = Zmp + Nmn − M

Definition: Half-Life

The time required for the number of radioactive nuclei to reduce to half of its initial value is called the half-life T1/2.

\[\frac{N_0}{2}=N_0e^{-\lambda T_{1/2}}\]

\[T_{1/2}=\frac{\ln2}{\lambda}=\frac{0.693}{\lambda}\]

Definition: Average Life

The average time for which a radioactive nucleus exists before decay is called the mean (average) life τ.

τ = \[\frac {1}{λ}\]

Definition: Chain Reaction

A self-sustaining sequence of fission reactions in which neutrons produced in one fission cause further fissions is called a chain reaction.

Definition: Nuclear Reactor

A device in which nuclear fission is carried out in a controlled manner to produce energy is called a nuclear reactor.

Definition: Nuclear Fission

The process in which a heavy nucleus splits into two lighter nuclei with the release of energy is called nuclear fission.

Definition: Daughter Nucleus

The nucleus formed after radioactive decay is called the daughter nucleus.

Definition: Parent Nucleus

The original unstable nucleus which undergoes decay is called the parent nucleus.

Definition: Radioactive Decay

The spontaneous transformation of an unstable nucleus into a more stable nucleus by emission of particles or radiation is called radioactive decay.

Definition: Nuclear Force

The force that binds protons and neutrons (nucleons) inside the nucleus is called the nuclear force or strong force.

Definition: Binding Energy

The energy required to completely separate the nucleons of a nucleus and take them to infinity.

Definition: Nuclear Fusion

The process in which two light nuclei combine to form a heavier nucleus with the release of energy is called nuclear fusion.

Definition: Atom

The smallest indivisible particles of matter proposed by early philosophers are called atoms.

Definition: Nucleus

The central, tiny, positively charged part of an atom that contains almost all of its mass is called the nucleus.

Definition: Radioactive Decay

The spontaneous disintegration of an unstable nucleus accompanied by emission of radiation is called radioactive decay.

Formulae [7]

Formula: Rydberg Formula

\[\frac{1}{\lambda}=R\left(\frac{1}{n^2}-\frac{1}{m^2}\right)\]

Formula: Quantization of Angular Momentum

mvr = \[\frac {nh}{2π}\]

where

  • m = mass of electron
  • v = velocity
  • r = radius of orbit
  • n =1,2,3,… (principal quantum number)
  • h = Planck’s constant
Formula: Bohr’s Radius

\[r_n=a_0\frac{n^2}{Z}\]

Formula: Nuclear Density

\[\rho=\frac{mA}{\frac{4}{3}\pi R^3}\]

After substituting R = R0A1/3:

\[\rho=\frac{3m}{4\pi R_0^3}\]

Formula: Binding Energy

EB = ΔMc2

Binding Energy in terms of Protons and Neutrons:

EB= (Zmp+ NmnM)c2

Binding Energy using Atomic Masses:

EB = [ZmH+ Nmn M]c2

Formula: Q-value (Energy Released in Fission)

Q = [mparent mproducts]c2

Example form used in fission:

Q = [mUm1 m2 (neutron masses)]c2

Formula: Q-value (Energy Released in Fusion)

Q = [Mass of reactants Mass of products]c2

Example used in fusion inside the Sun:

Q = [4mp mα2me]c2

Theorems and Laws [2]

The ground state energy of the hydrogen atom is -13.6 eV. The kinetic and potential energy of the electron in the second excited state is respectively ______ 

The ground state energy of the hydrogen atom is -13.6 eV. The kinetic and potential energy of the electron in the second excited state is respectively 1.51 eV, -3.02 eV.

Explanation:

For second excited state n = 3

The total energy in the third orbit

`E_3 = (-13.6)/9`eV = -1.51 eV

K.E. = -T.E. = 1.51 eV

P.E. = 2.T.E. = -3.32 eV

Law: Law of Radioactive Decay

Statement

The rate of decay of a radioactive substance at any instant is directly proportional to the number of undecayed nuclei present at that instant.

Proof / Mathematical Derivation

Let N (t) be the number of undecayed nuclei at time t.

The rate of decay is proportional to N (t):

\[\frac {dN}{dt}\] ∝ -N (t)

Introducing proportionality constant λ (decay constant):

\[\frac{dN}{dt}=-\lambda N(t)\]

Separating variables:

\[\frac{dN}{N}=-\lambda dt\]

Integrating from N0 at t = 0 to N at time t:

\[\int_{N_0}^N\frac{dN}{N}=-\lambda\int_0^tdt\]

\[\ln\left(\frac{N}{N_0}\right)=-\lambda t\]

\[N=N_0e^{-\lambda t}\]

This is the Radioactive Decay Law.

Conclusion

Radioactive decay follows an exponential law. The number of undecayed nuclei and the activity decrease exponentially with time. The half-life and mean life are constants characteristic of a given radioactive substance and depend only on the decay constant λ\lambdaλ.

Key Points

Key Points: Structure of the Atom and Nucleus
  • The structure of an atom and its nucleus was developed from the discovery of electrons by J.J. Thomson and alpha particle scattering experiments by Rutherford.
  • An atom consists of electrons, protons, and neutrons, with protons and neutrons in the nucleus and electrons revolving in stationary orbits.
  • The maximum number of electrons in a shell is given by 2n², and the shells are named K, L, M, N, O, P, and Q.
Key Points: Geiger-Marsden Experiment
  • In this experiment, alpha particles were fired at a thin gold foil to study the structure of the atom.
  • Most alpha particles passed straight through, but some were deflected at different angles.
  • A very few particles were deflected through large angles, showing that most of the mass and positive charge of the atom is concentrated in a small region.
Key Points: Rutherford's Atomic Model
  • Rutherford said that almost all the mass and positive charge of an atom are concentrated in a tiny central nucleus.
  • The nucleus is very small compared to the atom, so most of the atom is empty space.
  • Electrons move around the nucleus in circular orbits like planets around the Sun.
  • Large deflection of some alpha particles was due to their close approach to the dense nucleus.
  • The model failed because revolving electrons should lose energy and fall into the nucleus, but atoms are stable and do not continuously emit radiation.
Key Points: Limitations of Bohr's Model
  • Bohr’s model could explain only the hydrogen spectrum and failed to explain the spectra of other atoms. It also could not explain the fine structure of hydrogen lines.
  • It could not explain why some spectral lines are brighter (more intense) than others.
  • The idea of fixed stable orbits was assumed without proper theoretical proof, so the model was not fully satisfactory.
Key Points: Nuclear Energy
  • Nuclear reactions release much more energy (in MeV) than chemical reactions (in eV).
  • For the same amount of fuel, nuclear energy is nearly a million times greater than chemical energy.
  • Nuclear energy is produced by fission (splitting heavy nuclei) and fusion (joining light nuclei).
  • The energy comes from the mass defect and the binding energy of the nucleus.
Key Points: Units of Atomic and Subatomic Mass
  • Three units are used to measure atomic masses:
    kg, atomic mass unit (u), and eV/c2.
  • Atomic mass unit (u):
    1 u = \[\frac {1}{12}\] of carbon-12 atom mass
    1 u = 1.66 × 10−27
    1 u = 931.5, MeV/c2.
  • Mass–energy relation:
    From E = mc2, mass can be expressed in energy units (eV/c2).
    Proton and neutron ≈ 1 u each; electron mass is much smaller.
Key Points: Nuclear Forces
  • The nuclear force is extremely strong at very short distances.
  • It acts only within a few femtometres and becomes zero beyond that.
  • It holds protons and neutrons together by overcoming proton–proton repulsion.
  • It acts the same between all nucleons, regardless of their charge.
Key Points: De Broglie's Explanation
  • De Broglie said every moving particle has a wave nature.
    λ = \[\frac {h}{mv}\]
  • Electrons in atoms behave like standing waves, not just particles.
  • Stable orbits form only when the orbit length equals whole multiples of the wavelength:
    2πr = nλ
  • Only certain orbits are allowed, because the wavelength must fit exactly in the orbit.
  • This explains Bohr’s rule:
    mvr = \[\frac {nh}{2π}\] (angular momentum is quantised).

Important Questions [20]

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