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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता ११ वी

Write the first four members of the homologous series that begins with CH3CHO. Also, write down their general molecular formula.

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प्रश्न

Write the first four members of the homologous series that begins with CH3CHO. Also, write down their general molecular formula.

तक्ता
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उत्तर

No. Name of compound and molecular formula Structural formula
1. Acetaldehyde (CH3CHO)

\[\begin{array}{cc}\phantom{...}\ce{O}\\
\phantom{...}||\\\ce{H3C - C - H}\end{array}\]

2. Propionaldehyde (C2H5CHO) \[\begin{array}{cc}\phantom{..........}\ce{O}\\
\phantom{..........}||\\\ce{H3C - CH2 - C - H}\end{array}\]
3. Butyraldehyde (C3H7CHO) \[\begin{array}{cc}\phantom{.................}\ce{O}\\
\phantom{.................}||\\\ce{H3C - CH2 - CH2 - C - H}\end{array}\]
4. Valeraldehyde (C4H9CHO) \[\begin{array}{cc}\phantom{....................}\ce{O}\\
\phantom{....................}||\\\ce{H3C - (CH2)2 - CH2 - C - H }\end{array}\]

Comparing these molecular formulae and assigning the number of carbon atoms as ‘n’, the following general formula is deduced: CnH2nO/CnH2n-1CHO (where n = 1,2,3,...)

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पाठ 14: Basic Principles of Organic Chemistry - Exercises [पृष्ठ २३१]

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बालभारती Chemistry [English] Standard 11 Maharashtra State Board
पाठ 14 Basic Principles of Organic Chemistry
Exercises | Q 3. A. | पृष्ठ २३१

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\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{....................}\\
\ce{CH3 - C - CH - CH2 - CH2 - CH3}\\
|\phantom{.....}|\phantom{...............}\\
\ce{CH3}\phantom{..}\ce{CH3}\phantom{.............}
\end{array}\]


Identify primary, secondary, tertiary and quaternary carbon in the following compounds.

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH - CH2 - CH2 - CH3}\\
\phantom{}|\phantom{....}|\phantom{...............}\\
\phantom{}\ce{CH3}\phantom{.}\ce{CH3}\phantom{.............}
\end{array}\]


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\[\begin{array}{cc}
\ce{CH3}\phantom{..................}\\
|\phantom{....................}\\
\ce{CH3 - C - CH - CH2 - CH2 - CH3}\\
\phantom{}|\phantom{....}|\phantom{................}\\
\phantom{.}\ce{CH3\phantom{.}CH3}\phantom{..............}
\end{array}\]


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\[\ce{CH3 -CH2 -\overset{⊕}{C}H -CH2 -CH3}\]


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\begin{array}{cc}
\ce{CH3}\phantom{..................}\\
|\phantom{....................}\\
\ce{CH3 - C - CH - CH2 - CH2 - CH3}\\
|\phantom{....}|\phantom{................}\\
\ce{CH3}\ce{CH3}\phantom{..............}
\end{array}


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\[\ce{HCONHCH3}\]


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\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{....................}\\
\ce{CH3 - C - CH - CH2 - CH2 - CH3}\\
|\phantom{....}|\phantom{................}\\
\ce{CH3}\phantom{.}\ce{CH3}\phantom{..............}\\
\end{array}\]


Identify primary, secondary, tertiary and quaternary carbon in the following compound.

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{....................}\\
\ce{CH3 - C - CH - CH2 - CH2 - CH3}\\
|\phantom{.....}|\phantom{................}\\
\ce{CH3}\phantom{.}\ce{CH3}\phantom{..............}
\end{array}\]


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\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{....................}\\
\ce{CH3 - C - CH - CH2 - CH2 - CH3}\\
|\phantom{....}|\phantom{................}\\
\ce{CH3}\phantom{.}\ce{CH3}\phantom{..............}
\end{array}\]


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\[\begin{array}{cc}
\ce{CH3}\phantom{..................}\\
|\phantom{....................}\\
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|\phantom{....}|\phantom{................}\\
\ce{CH3}\phantom{.}\ce{CH3}\phantom{..............}
\end{array}\]


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