मराठी

What is the Effect of Adding a Catalyst on Activation Energy (Ea)

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प्रश्न

What is the effect of adding a catalyst on Activation energy (Ea)

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उत्तर

The catalyst provides an alternate pathway or reaction mechanism by reducing the activation energy (Ea) between reactants and products.

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2016-2017 (March) All India Set 3

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संबंधित प्रश्‍न

The rate of the chemical reaction doubles for an increase of 10 K in absolute temperature from 298 K. Calculate Ea.


The rate constant for the decomposition of hydrocarbons is 2.418 × 10−5 s−1 at 546 K. If the energy of activation is 179.9 kJ/mol, what will be the value of pre-exponential factor?


In the Arrhenius equation for a first order reaction, the values of ‘A’ of ‘Ea’ are 4 × 1013 sec−1 and 98.6 kJ mol−1 respectively. At what temperature will its half life period be 10 minutes?

[R = 8.314 J K−1 mol−1]


The decomposition of a hydrocarbon has value of rate constant as 2.5×104s-1 At 27° what temperature would rate constant be 7.5×104 × 3 s-1if energy of activation is  19.147 × 103 J mol-1 ?


The chemical reaction in which reactants require high amount of activation energy are generally ____________.


Which of the following statements are in accordance with the Arrhenius equation?

(i) Rate of a reaction increases with increase in temperature.

(ii) Rate of a reaction increases with decrease in activation energy.

(iii) Rate constant decreases exponentially with increase in temperature.

(iv) Rate of reaction decreases with decrease in activation energy.


Mark the incorrect statements:

(i) Catalyst provides an alternative pathway to reaction mechanism.

(ii) Catalyst raises the activation energy.

(iii) Catalyst lowers the activation energy.

(iv) Catalyst alters enthalpy change of the reaction.


Oxygen is available in plenty in air yet fuels do not burn by themselves at room temperature. Explain.


What happens to most probable kinetic energy and the energy of activation with increase in temperature?


A first-order reaction is 50% complete in 30 minutes at 300 K and in 10 minutes at 320 K. Calculate activation energy (Ea) for the reaction. [R = 8.314 J K−1 mol−1]

[Given: log 2 = 0.3010, log 3 = 0.4771, log 4 = 0.6021]


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