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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

What is the Action of P-toluenesulphonychloride on Ethylamine and Diethylamine ?

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प्रश्न

What is the action of p-toluenesulphonychloride on ethylamine and diethylamine?

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उत्तर

It help to distinguish between primary and secondary amines

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2017-2018 (March)

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संबंधित प्रश्‍न

Which among the following molecular formulae represents urotropine?

(a) C6H12N4

(b) C6H24H4                    

(c) C6H12N4O2

(d) C6H24N4O2


Convert 3-Methylaniline into 3-nitrotoluene.


Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.

CH3(CH2)2NH2


Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.

CH3NHCH(CH3)2


Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.

(CH3)3CNH2


Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.

(CH3CH2)2NCH3


Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.

m−BrC6H4NH2


Give one chemical test to distinguish between the following pair of compounds.

Ethylamine and aniline


Give one chemical test to distinguish between the following pair of compounds.

Aniline and benzylamine


Account for the following:

pKb of aniline is more than that of methylamine.


Account for the following:

Ethylamine is soluble in water, whereas aniline is not.


Account for the following:

Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.


How will you convert ethanoic acid into propanoic acid?


How will you convert nitromethane into dimethylamine?


Accomplish the following conversion:

Benzoic acid to aniline


Complete the following reaction:

\[\ce{C6H5N2Cl + C2H5OH ->}\]


Complete the following reaction:

\[\ce{C6H5N2Cl ->[(i) HBF4][(ii) NaNO2/Cu, \Delta]}\]


Give reasons  Although –NH2 is o/p directing group, yet aniline on nitration gives a significant amount of m-nitroaniline


How are ethylamine and ethyl methyl amine distinguished by using nitrous acid?


Write the IUPAC name of the given compound :


Give simple chemical tests to distinguish between the following pair of compounds:

Benzaldehyde and Benzoic acid


An organic compound (A) with molecular formula C3H7NO on heating with Br2 and KOH forms a compound (B). Compound (B) on heating with CHCl3 and alcoholic KOH produces a foul-smelling compound (C) and on reacting with C6H5SO2Cl forms a compound (D) which is soluble in alkali. Write the structure of (A), (B), (C) and (D).


Do the following conversions in not more than two steps:


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