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प्रश्न
How will you distinguish between Ammonium hydroxide and Sodium hydroxide using copper sulphate solution?
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उत्तर
Ammonium hydroxide when added to copper sulphate drop-wise forms a pale blue ppt. of copper hydroxide which dissolves in excess of ammonium hydroxide to form a deep blue solution of tetrammine copper sulphate.
CuSO4 + 2NH4OH 
Cu OH2 + NH4 2SO4
pale blue ppt colourless in solution
With excess of NH OH ppt. dissolves
Cu OH2 + NH4 2SO4 + 2NH4OH |Cu NH3 4|SO4 + 4H2O
Tetrammine
Copper II sulphate
Sodium hydroxide when added to copper sulphate drop-wise forms a pale blue ppt. of copper hydroxide which is insoluble in excess of sodium hydroxide solution.
CuSO4 + 2NaOH Cu OH2 + Na2SO4
pale blue ppt colourless
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संबंधित प्रश्न
Choose the correct answer from the options given below:
A chloride which forms a precipitate that is soluble in excess of ammonium hydroxide is:
1) Calcium chloride
2) Ferrous chloride
3) Ferric chloride
4) Copper chloride
You are provided with PbCO3, ZnCO3 and CaCO3. How will you identify these cations?
State what do you observe when:
Ammonium hydroxide is added to iron (III) sulphate solution.
State two relevant observations of the following:
Ammonium hydroxide solution is added to zinc nitrate solution in minimum quantities and then in excess.
Identify the cation of the following case:
NH4OH solution when added to solution (B) gives white ppt. which does not dissolve in excess.
Write balanced equation copper sulphate solution with ammonium hydroxide solution.
The salt solution which does not react with ammonium hydroxide is ______.
Identify the cation in the following case:
Ammonium hydroxide solution when added to Solution B gives a white precipitate which does not dissolve in excess of ammonium hydroxide solution.
Rita was given an unknown salt for identification. She prepared a solution of the salt and divided it into two parts.
- To the first part of the salt solution, she added a few drops of ammonium hydroxide and obtained a reddish-brown precipitate.
- To the second part of the salt solution, she added a few drops of silver nitrate solution and obtained a white precipitate.
Name:
- The cation present and
- The anion present in the salt given for identification.
Write balanced equation:
Copper sulphate solution with ammoni um hydroxide solution.
