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प्रश्न
How will you distinguish between Ammonium hydroxide and Sodium hydroxide using copper sulphate solution?
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उत्तर
Ammonium hydroxide when added to copper sulphate drop-wise forms a pale blue ppt. of copper hydroxide which dissolves in excess of ammonium hydroxide to form a deep blue solution of tetrammine copper sulphate.
CuSO4 + 2NH4OH 
Cu OH2 + NH4 2SO4
pale blue ppt colourless in solution
With excess of NH OH ppt. dissolves
Cu OH2 + NH4 2SO4 + 2NH4OH |Cu NH3 4|SO4 + 4H2O
Tetrammine
Copper II sulphate
Sodium hydroxide when added to copper sulphate drop-wise forms a pale blue ppt. of copper hydroxide which is insoluble in excess of sodium hydroxide solution.
CuSO4 + 2NaOH Cu OH2 + Na2SO4
pale blue ppt colourless
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संबंधित प्रश्न
What happens when ammonia solution is added first dropwise and then in excess to the following solution:
ZnSO4
Write a balanced equation for this reaction.
On adding dilute ammonia solution to a colourless solution of a salt, a white gelatinous precipitate appears. This precipitate however dissolves on addition of excess of ammonia solution. Identify (choose from Na, Al, Zn, Pb, Fe)
Which metal salt solution was used?
Name the method used for preparation of the following salt from the list given below:
Zinc ion and Lead ion.
How would you distinguish between Zn2+ and Pb2+ ions, using ammonium hydroxide solution?
Distinguish between the given pair of compounds using the test given within brackets:
A lead salt and a zinc salt (using excess ammonium hydroxide)
The following table shows the tests a student performed on four different aqueous solutions which are X,Y,Z and W. Based on the observations provided, Identify the cation present
|
Chemical Test |
Observation | Conclusion |
| To Solution X, ammonium hydroxide is added in minium quantity first and then in excess | A dirty white precipitate is formed which dissolves in excess to form a clear solution | (i) |
| To Solution Y, ammonium hydroxide is added in minimum quantity first and then in excess | A pale blue precipitate is formed which dissolves in excess to form a clear inky blue solution | (ii) |
| To solution W, A small quantity of sodium hydroxide solution is added and then in excess | A white precipitate is formed which remains insoluble | (iii) |
| To a salt Z, calcium hydroxide solution is added and then heated | A pungent smelling gas turning moist red litmus paper blue is obtained | (iv) |
Identify the cation of the following case:
NaOH solution when added to solution (C) gives white ppt. which insoluble in excess.
Write balanced equation:
Copper sulphate solution with ammoni um hydroxide solution.
Write balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
Write balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
