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प्रश्न
How will you distinguish between Ammonium hydroxide and Sodium hydroxide using copper sulphate solution?
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उत्तर
Ammonium hydroxide when added to copper sulphate drop-wise forms a pale blue ppt. of copper hydroxide which dissolves in excess of ammonium hydroxide to form a deep blue solution of tetrammine copper sulphate.
CuSO4 + 2NH4OH 
Cu OH2 + NH4 2SO4
pale blue ppt colourless in solution
With excess of NH OH ppt. dissolves
Cu OH2 + NH4 2SO4 + 2NH4OH |Cu NH3 4|SO4 + 4H2O
Tetrammine
Copper II sulphate
Sodium hydroxide when added to copper sulphate drop-wise forms a pale blue ppt. of copper hydroxide which is insoluble in excess of sodium hydroxide solution.
CuSO4 + 2NaOH Cu OH2 + Na2SO4
pale blue ppt colourless
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संबंधित प्रश्न
On adding dilute ammonia solution to a colourless solution of a salt, a white gelatinous precipitate appears. This precipitate however dissolves on addition of excess of ammonia solution. Identify (choose from Na, Al, Zn, Pb, Fe)
Which metal salt solution was used?
How will you distinguish NH4OH solution from NaOH solution?
Fill in the blank.
The salt which will not react with NH4OH solution ______[ZnCl2, CuCl2 / NH4Cl/ FeCl2]
Three test tubes contain calcium nitrate solution, zinc nitrate solution and lead nitrate solution.Describe the effect of Adding ammonium hydroxide to each portion in turn till it is in excess.
Write the observation for the following :
NH4OH is added first in a small quantity and then in excess to a solution of copper sulphate.
What would you observe in the following cases:
Ammonium hydroxide is first added in a small quantity and then in excess to a solution of copper sulphate.
Identify the cation of the following case:
NaOH solution when added to solution (A) gives a reddish brown precipitate
Write balanced equation :
Copper sulphate solution with ammonium hydroxide solution.
Write a balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
Write balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
