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प्रश्न
Give one chemical test to distinguish between the following pair of compounds.
Ethylamine and aniline
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उत्तर
Ethylamine is a primary aliphatic amine, while aniline is a primary aromatic amine. They can be differentiated by azo dye test.
Azo dye test: In this, aromatic primary amine reacts with HNO2 (NaNO2 + dil. HCl) at 273 – 278 K and then reacts with alkaline solution of 2-naphthol (β-naphthol) to give a deep yellow, orange or red colored dye.
Aliphatic primary amines under the above conditions rapidly release nitrogen gas with the formation of primary alcohols, i.e., the solution remains transparent.
\[\ce{\underset{Ethylamine}{C2H5NH2} + HONO ->[273 - 278 K] \underset{ethyl alcohol}{C2H5OH} + H2O + N2 ^}\]
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संबंधित प्रश्न
Write the IUPAC name of the following compound and classify it as primary, secondary and tertiary amine.
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An aromatic compound ‘A’ on treatment with aqueous ammonia and heating forms compound ‘B’ which on heating with Br2 and KOH forms a compound ‘C’ of molecular formula C6H7N. Write the structures and IUPAC names of compounds A, B and C.
Complete the following reaction:
\[\ce{C6H5N2Cl + C2H5OH ->}\]
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\[\ce{C6H5NH2 + Br2 (aq) ->}\]
Complete the following reaction:
\[\ce{C6H5NH2 + (CH3CO)2O ->}\]
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