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Explain why does colour of KMNOX4 disappear when oxalic acid is added to its solution in acidic medium. - Chemistry

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प्रश्न

Explain why does colour of \[\ce{KMNO4}\] disappear when oxalic acid is added to its solution in acidic medium.

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लघु उत्तर
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उत्तर

\[\ce{KMnO4}\] acts as oxidising agent. It oxidises oxalic acid to \[\ce{CO2}\] and itself changes to \[\ce{Mn^2+}\] ion which is colourless.

\[\ce{5C2O^{2-}4 + \underset{(Coloured)}{2MnO^-4} + 16H+ -> \underset{(Coloured)}{2Mn^2+} + 8H2O + 10CO2}\]

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पाठ 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १११]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
पाठ 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 44. | पृष्ठ १११

संबंधित प्रश्‍न

Explain why is Fe3+ more stable than Fe2+?


Which metal in the first transition series (3d series) exhibits + 1 oxidation state most frequently and why?


Account for the following:

Mn shows the highest oxidation state of +7 with oxygen but with fluorine, it shows oxidation state of +4.


`E_((M^(2+)/M)`

Cr Mn Fe Co Ni Cu
-0.91 -1.18 -0.44 -0.28 -0.25 -0.34

From the given data of E0 values, answer the following questions :

(1) Why is `E_(((Cu^(2+))/(Cu)))` value exceptionally positive

(2) Why is `E_(((Mn^(2+))/(Mn)))` value is highly negative as compared to other elements

(3) Which is the stronger reducing agents Cr2+ or Fe2+ ? Give Reason.


An antifriction alloy made up of antimony with tin and copper, which is extensively used in machine bearings is called _______.

(A) Duralumin

(B) Babbitt metal

(C) Spiegeleisen

(D) Amalgam


Following are the transition metal ions of 3d series:

Ti4+, V2+, Mn3+, Cr3+

(Atomic numbers: Ti = 22, V = 23, Mn = 25, Cr = 24)

Answer the following:

1) Which ion is most stable in an aqueous solution and why?

2) Which ion is a strong oxidising agent and why?

3) Which ion is colourless and why?


Maximum magnetic moment is shown by ____________.


Ionisation enthalpies of Ce, Pr and Nd are higher than Th, Pa and U. Why?


Identify A to E and also explain the reactions involved.


Identify the metal and justify your answer.

\[\ce{MO3F}\]


Mention any three processes where transition metals act as catalysts.


A violet compound of manganese (A) decomposes on heating to liberate oxygen and compounds (B) and (C) of manganese are formed. Compound (C) reacts with KOH in the presence of potassium nitrate to give compound (B). On heating compound (C) with conc. \[\ce{H2SO4}\] and \[\ce{NaCl}\], chlorine gas is liberated and a compound (D) of manganese along with other products is formed. Identify compounds A to D and also explain the reactions involved.


Fill in the blanks by choosing the appropriate word(s) from those given in the brackets:

(activation energy, Threshold energy, increased, lowered, partially, full, d-d transition, Benzoic acid, benzaldehyde)

Only those transition metal ions will be coloured which have ______ filled d-orbitals facilitating ______.


On strong heating AgNO3, the gases evolved are:-


The given graph shows the trends in melting points of transition metals:

Explain the reason why Cr has the highest melting point and manganese (Mn) has a lower melting point.


Consider the following standard electrode potential values:

\[\ce{Sn^{2+}_{ (aq)} + 2e^- -> Sn_{(s)}}\]; E0 = −0.14 V

\[\ce{Fe^{3+}_{ (aq)} + e^- -> Fe^{2+}_{ (aq)}}\]; E0 = +0.77 V

What is the cell reaction and potential for the spontaneous reaction that occurs?


Account for the following:

Copper has an exceptionally positive `"E"_("M"^(2+)//"M")^0` value.


Give two similarities in the properties of Sc and Zn.


Account for the following:

Zirconium (Zr) and Hafnium (Hf) are difficult to separate.


Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:

Oxidation states


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