Advertisements
Advertisements
प्रश्न
Draw the cis and trans structures of hex-2-ene. Which isomer will have higher b.p. and why?
Advertisements
उत्तर
Hex-2-ene is represented as:
\[\ce{CH3 - CH = CH - CH2 - CH2 - CH3}\]
Geometrical isomers of hex-2-ene are:
\[\begin{array}{cc}
\phantom{.............}\ce{H3C}\phantom{.........}\ce{CH2 - CH2 - CH3}\\
\backslash\phantom{.......}/\\
\ce{C = C}\\
/\phantom{.......}\backslash\\
\ce{H}\phantom{.........}\ce{H}\end{array}\]
cis-isomer
\[\begin{array}{cc}
\phantom{.}\ce{H3C}\phantom{......}\ce{H}\\
\backslash\phantom{.......}/\\
\ce{C = C}\\
/\phantom{.......}\backslash\\
\phantom{..............}\ce{H}\phantom{.......}\ce{CH2 - CH2 - CH3}\end{array}\]
trans-isomer
The dipole moment of cis-compound is a sum of the dipole moments of C–CH3 and C–CH2CH2CH3 bonds acting in the same direction.
The dipole moment of trans-compound is the resultant of the dipole moments of C–CH3 and C–CH2CH2CH3 bonds acting in opposite directions.
Hence, cis-isomer is more polar than trans-isomer. The higher the polarity, the greater is the intermolecular dipole-dipole interaction and the higher will be the boiling point. Hence, cis-isomer will have a higher boiling point than trans-isomer.
APPEARS IN
संबंधित प्रश्न
Write IUPAC name of the product obtained by the ozonolysis of the following compound:
3,4-Dimethyl-hept-3-ene
Write IUPAC name of the product obtained by the ozonolysis of the following compound:
2-Ethylbut-1-ene
Find out the type of isomerism exhibited by the following pair.
CH3 – CH2 – NH – CH2 - CH3 and CH3 - NH - CH2 - CH2 - CH3
Find out the type of isomerism exhibited by the following pair.
\[\begin{array}{cc}
\ce{CH3 - CH - CH2 - CH3 and CH3 - CH2 - O - CH2 - CH3}\\|\phantom{...........................................}\\
\ce{OH}\phantom{.........................................}\end{array}\]
Find out the type of isomerism exhibited by the following pair.
Find out the type of isomerism exhibited by the following pair.
Choose the correct option.
Which type of isomerism is possible in CH3 CHCHCH3?
What type(s) of isomerism is(are) shown by [Co(NH3)4Br2]Cl?
But-1-ene and But-2-ene are examples of ____________.
Which of the following is a functional isomer of pentan-2-ol?
The type of isomerism possible in 2-butene is ____________.
In which of the following, functional group isomerism is not possible?
Which of the following pairs are position isomers?
| I. | \[\begin{array}{cc} \phantom{.......................}\ce{O}\\ \phantom{.......................}||\\ \ce{CH3 - CH2 - CH2 - CH2 - C - H} \end{array}\] |
| II. | \[\begin{array}{cc} \phantom{.................}\ce{O}\\ \phantom{.................}||\\ \ce{CH3 - CH2 - CH2 - C - H} \end{array}\] |
| III. | \[\begin{array}{cc} \ce{CH3 - CH2 - C - CH2 - CH3}\\ \phantom{}||\\ \phantom{}\ce{O} \end{array}\] |
| IV. | \[\begin{array}{cc} \ce{CH3 - CH - CH2 - C - H}\\ \phantom{...}|\phantom{............}||\phantom{}\\ \phantom{...}\ce{CH3}\phantom{.........}\ce{O}\phantom{} \end{array}\] |
(i) I and II
(ii) II and III
(iii) II and IV
(iv) III and IV
Consider structures I to VII and answer the question:
| I. | CH3 – CH2 – CH2 – CH2 – OH |
| II. | \[\begin{array}{cc} \ce{CH3 - CH2 - CH - CH3}\\ \phantom{.....}|\\ \phantom{.......}\ce{OH} \end{array}\] |
| III. | \[\begin{array}{cc} \phantom{...}\ce{CH3}\\ \phantom{}|\\ \ce{CH3 - C - CH3}\\ \phantom{}|\\ \phantom{..}\ce{OH} \end{array}\] |
| IV. | \[\begin{array}{cc} \ce{CH3 - CH - CH2 - OH}\\ |\phantom{........}\\ \ce{CH3}\phantom{......} \end{array}\] |
| V. | CH3 – CH2 – O – CH2 – CH3 |
| VI. | CH3 – O – CH2 – CH2 – CH3 |
| VII. | \[\begin{array}{cc} \ce{CH3 - O - CH - CH3}\\ \phantom{...}|\\ \phantom{......}\ce{CH3} \end{array}\] |
Identify the pairs of compounds which are functional group isomers.
Compounds with same molecular formula but differing in their structures are said to be structural isomers. What type of structural isomerism is shown by
CH3 – S – CH2 – CH2 – CH3
And
\[\begin{array}{cc}
\phantom{.....................}\ce{CH3}\\
\phantom{................}/\\
\phantom{}\ce{CH3 - S - CH}\\
\phantom{...............}\backslash\\
\phantom{....................}\ce{CH3}
\end{array}\]
Assertion (A): Pent- 1- ene and pent- 2- ene are position isomers.
Reason (R): Position isomers differ in the position of functional group or a substituent.
Tautomerism is exhibited by ______.
Which of the following does NOT exhibit geometrical isomerism?
Which type of isomerism can not be shown by benzaldoxime?
Which one of the following pairs are called position isomers?
The correct stereochemical name of
How many structural isomers possible of the molecular formula C3H6O (excluding enol form)?
The number of acyclic structural isomers (including geometrical isomers) for pentene are ______.
Which of the following pairs of compounds are positional isomers?
Which of the following reactions will not produce a racemic product?
The number of geometrical isomers from [Co(NH3)3(NO2)3] is ______.
Which of the following pairs of compounds is an example of position isomerism?
