मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

A first order reaction has a rate constant 1.15 × 10^−3 s−1. How long will 5 g of this reactant take to reduce to 3 g?

Advertisements
Advertisements

प्रश्न

A first order reaction has a rate constant 1.15 × 10−3 s−1. How long will 5 g of this reactant take to reduce to 3 g?

संख्यात्मक
Advertisements

उत्तर

For a first-order reaction,

a = 5 g

(a – x) = 3 g

k = 1.15 × 10−3 s−1

t = `2.303/k log  a/((a - x))`

= `2.303/(1.15 xx 10^-3) log  (5)/(3)`

= 2.00 × 103 (log 5 − log 3)

= 2.00 × 103 (0.6990 − 0.4771)

= 2.00 × 103 × 0.2219

= 443.8

≈ 444 S

shaalaa.com
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 3: Chemical Kinetics - Intext Questions [पृष्ठ ७८]

APPEARS IN

एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 3 Chemical Kinetics
Intext Questions | Q 3.5 | पृष्ठ ७८

संबंधित प्रश्‍न

For the decomposition of azoisopropane to hexane and nitrogen at 543 K, the following data are obtained.

t (sec) P(mm of Hg)
0 35.0
360 54.0
720 63.0

Calculate the rate constant.


Define order of reaction. How does order of a reaction differ from molecularity for a complex reaction? 


 A first order reaction is 50% complete in 25 minutes. Calculate the time for 80% completion of the reaction.


Which of the following graphs is correct for a first order reaction?


With the help of an example explain what is meant by pseudo first order reaction.


First order reaction is 50% complete in 1.26 × 1014s. How much time could it take for 100% completion?


Time required to decompose SO2Cl2 to half of its initial concentration is 60 minutes. If the de-composite is a first order reaction, calculated the rate constant of the reaction-


In a first order reaction the concentration of reactants decreases from 400mol L-1 to 25 mol L-1 in 200 seconds. The rate constant for the reaction is ______.


The decomposition of formic acid on gold surface follows first-order kinetics. If the rate constant at 300 K is 1.0 × 10−3 s−1 and the activation energy Ea = 11.488 kJ mol−1, the rate constant at 200 K is ______ × 10−5 s−1. (Round off to the Nearest Integer)

(Given R = 8.314 J mol−1 K−1)


A definite volume of H2O2 undergoing spontaneous decomposition required 22.8 c.c. of standard permanganate solution for titration. After 10 and 20 minutes respectively the volumes of permanganate required were 13.8 and 8.25 c.c. The time required for the decomposition to be half completed is ______ min.


The slope in the plot of ln[R] vs. time for a first order reaction is ______.


The slope in the plot of `log  ["R"]_0/(["R"])` Vs. time for a first-order reaction is ______.


Define first-order reaction.


Write the equation for integrated rate law for a first order reaction.


Show that `t_(1/2)= 0.693/k` for first reaction.


Write the unit of rate constant [k] for the first order reaction.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×