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Balbharati solutions for केमिस्ट्री [अंग्रेजी] कक्षा १२ महाराष्ट्र राज्य बोर्ड chapter 1 - Solid State [Latest edition]

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Balbharati solutions for केमिस्ट्री [अंग्रेजी] कक्षा १२ महाराष्ट्र राज्य बोर्ड chapter 1 - Solid State - Shaalaa.com
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Solutions for Chapter 1: Solid State

Below listed, you can find solutions for Chapter 1 of Maharashtra State Board Balbharati for केमिस्ट्री [अंग्रेजी] कक्षा १२ महाराष्ट्र राज्य बोर्ड.


Exercises
Exercises [Pages 25 - 27]

Balbharati solutions for केमिस्ट्री [अंग्रेजी] कक्षा १२ महाराष्ट्र राज्य बोर्ड 1 Solid State Exercises [Pages 25 - 27]

Choose the most correct answer.

1. i.Page 25

Molecular solids are ______.

  • crystalline solids

  • amorphous solids

  • ionic solids

  • metallic solids

1. ii.Page 25

Which of the following is n-type semiconductor?

  • Pure Si

  • Si doped with As

  • Si doped with Ga

  • Ge doped with ln

1. iii.Page 25

Choose the most correct answer.

In Frenkel defect, _______.

  • electrical neutrality of the substance is changed

  • density of the substance is changed

  • both cation and anion are missing

  • overall electrical neutrality is preserved

1. iv.Page 25

Choose the most correct answer.

In crystal lattice formed by bcc unit cell, the void volume is _______.

  • 68%

  • 74%

  • 32%

  • 26%

1. v.Page 26

The coordination number of atoms in bcc crystal lattice is ______.

  • 2

  • 4

  • 6

  • 8

1. vi.Page 26

Which of the following is not correct?

  • Four spheres are involved in the formation of a tetrahedral void.

  • The centres of spheres in octahedral voids are at the apices of a regular tetrahedron.

  • If the number of atoms is N, the number of octahedral voids is 2N.

  • If the number of atoms is N/2, the number of tetrahedral voids is N.

1. vii.Page 26

Choose the most correct answer.

A compound forms hcp structure. Number of octahedral and tetrahedral voids in 0.5 mole of substance is respectively _______. 

  • 3.011 × 1023, 6.022 × 1023

  • 6.022 × 1023, 3.011 × 1023

  • 4.011 × 1023, 2.011 × 1023

  • 6.011 × 1023, 12.022 × 1023

1. vii.Page 26

Pb has fcc structure with edge length of unit cell 495 pm. Radius of Pb atom is ______.

  • 205 pm

  • 185 pm

  • 260 pm

  • 175 pm

2.01Page 26

Answer the following in one or two sentences. 

What are the types of particles in each of the four main classes of crystalline solids?

2.02Page 26

Answer the following in one or two sentences.

Which of the three types of packing used by metals makes the most efficient use of space and which makes the least efficient use?

2.03Page 26

Answer the following in one or two sentences.

The following pictures show population of bands for materials having different electrical properties. Classify them as insulator, semiconductor or metal.

2.04Page 26

Answer the following in one or two sentences.

What is the unit cell?

2.05Page 26

Answer the following in one or two sentences.

How does the electrical conductivity of a semiconductor change with temperature? Why?

2.06Page 26

Answer the following in one or two sentences.

The picture represents bands of MOs for Si. Label valence band, conduction band, and band gap.

2.07Page 26

Answer the following in one or two sentences.

A solid is hard, brittle and electrically nonconductor. Its melt conducts electricity. What type of solid is it?

2.08Page 26

Answer the following in one or two sentences.

Mention two properties that are common to both hcp and ccp lattices.

2.09Page 26

Answer the following in one or two sentences.

Sketch a tetrahedral void.

2.10Page 26

What are ferromagnetic substances?

3.01 aPage 26

What is valence band?

3.01 bPage 26

What is conduction band?

3.02Page 26

Answer the following in brief.

Distinguish between ionic solids and molecular solids

3.03Page 26

Answer the following in brief.

Calculate the number of atoms in fcc unit cell.

3.04Page 26

Answer the following in brief.

How are the spheres arranged in first layer of simple cubic close-packed structures? How are the successive layers of spheres placed above this layer?

3.05Page 27

Answer the following in brief.

Calculate the packing efficiency of metal crystal that has simple cubic structure.

3.06.i.Page 27

What are paramagnetic substances?

3.06.ii.Page 27

Give examples of paramagnetic substances.

3.07Page 27

What are the consequences of the Schottky defect in crystals?

3.08Page 27

Answer the following in brief.

Cesium chloride crystallizes in a cubic unit cell with Cl ions at the corners and a Cs+ ion in the center of the cube. How many CsCl molecules are there in the unit cell?

3.09Page 27

Cu crystallizes in fcc unit cell with edge length of 495 pm. What is the radius of Cu atom?

3.1Page 27

Obtain the relationship between the density of a substance and the edge length of the unit cell.

4Page 27

The density of iridium is 22.4 g/cm3. The unit cell of iridium is fcc. Calculate the radius of iridium atom. Molar mass of iridium is 192.2 g/mol.

5Page 27

Aluminium crystallizes in a cubic close-packed structure with a unit cell edge length of 353.6 pm. What is the radius of Al atom? How many unit cells are there in 1.00 cm3 of Al? 

6Page 27

In ionic crystalline solid atoms of element Y form hcp lattice. The atoms of element X occupy one-third of tetrahedral voids. What is the formula of the compound?

7Page 27

How are tetrahedral and octahedral voids formed?

8Page 27

Third layer of spheres is added to second layer so as to form hcp or ccp structure. What is the difference between the addition of third layer to form these hexagonal close-packed structures?

9Page 27

An element with molar mass 27 g/mol forms a cubic unit cell with edge length of 405 p.m. If the density of the element is 2.7 g/cm3, what is the nature of the cubic unit cell?

10Page 27

An element has a bcc structure with a unit cell edge length of 288 pm. How many unit cells and a number of atoms are present in 200 g of the element? (1.16 × 1024, 2.32 × 1024)

11Page 27

Distinguish with the help of diagrams metal conductors, insulators and semiconductors from each other.

12Page 27

What are n-type semiconductors? Why is the conductivity of doped n-type semiconductor higher than that of pure semiconductor? Explain with diagram.

13. i.Page 27

Explain with a diagram the Frenkel defect.

13. ii.Page 27

What are the conditions for the formation of a Frenkel defect?

13. iii.Page 27

What are the consequences of Frenkel defects in crystals?

14Page 27

What is an impurity defect? What are its types? Explain the formation of vacancies through aliovalent impurity with example.

Solutions for 1: Solid State

Exercises
Balbharati solutions for केमिस्ट्री [अंग्रेजी] कक्षा १२ महाराष्ट्र राज्य बोर्ड chapter 1 - Solid State - Shaalaa.com

Balbharati solutions for केमिस्ट्री [अंग्रेजी] कक्षा १२ महाराष्ट्र राज्य बोर्ड chapter 1 - Solid State

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