Advertisements
Advertisements
प्रश्न
How are tetrahedral and octahedral voids formed?
Advertisements
उत्तर
- Two dimensional hexagonal close-packed layer has triangular voids which is formed by three spheres.
- When the triangular voids of the first layer are covered by spheres of the next layer, tetrahedral voids are formed. A tetrahedral void is surrounded by four spheres.
- The overlapping triangular voids from the two layers together form an octahedral void.
An octahedral void is surrounded by six spheres. - Thus, the depressions in which spheres of second layer rest are tetrahedral voids while the depressions in which no sphere rests are octahedral voids.

APPEARS IN
संबंधित प्रश्न
The density of iron crystal is 8.54-gram cm–3. If the edge length of the unit cell is 2.8 A° and atomic mass is 56 gram mol–1, find the number of atoms in the unit cell. (Given: Avogadro's number = 6.022x1023,1A° = 1x10-8 cm)
Answer the following in brief.
How are the spheres arranged in first layer of simple cubic close-packed structures? How are the successive layers of spheres placed above this layer?
Third layer of spheres is added to second layer so as to form hcp or ccp structure. What is the difference between the addition of third layer to form these hexagonal close-packed structures?
The number of tetrahedral voids are formed if the number of atoms in a crystal is N/2.
In hexagonal close packed (hep) structure, ____________ layer and ____________ layer have horizontal and vertical alignment.
A metal crystallizes in bcc lattice with edge length 4.48 Å. The radius of the metal atom is ___________ Å.
An element crystallises in a bee lattice with cell edge of 500 pm. The density of the element is 7.5 g cm-3. How many atoms are present in 300 g of metal?
The ratio of close-packed atoms to tetrahedral holes in cubic close packing is ____________.
A metallic element crystallises in simple cubic lattice. If edge length of the unit cell is 3Å, with density 8 g/cc, what is the number of unit cells in 100 g of the metal?
(Molar mass of metal = 108 g/mol)
The coordination number of each sphere in bcc lattice is ____________.
The coordination number of Rh in the complex [Rh(NH3)3(SCN)3] is ____________.
In ABCABC type arrangement of spheres, the coordination number of any sphere is __________.
Zinc forms hcp structure. What is the number of octahedral voids formed in 0.2 mol of it?
What is the coordination number of cation in ionic compound if the type of hole occupied by cation is cubic?
A metallic element crystallizes in simple cubic lattice. If edge length of the unit cell is 3Å, with density 8 g/cc, what is the number of unit cells in 108 g of the metal?
(Molar mass of metal = 100 g/mol)
What is the coordination number of atoms in bcc crystal lattice?
How much vacant space is present in hep crystal lattice?
Predict the type of cubic lattice of a solid element having edge length of 400 pm and density is 6.25 g/ml.
(Atomic mass of element = 60)
Calculate the total number of tetrahedral and octahedral voids formed in 0.6 mol of a compound if it forms hcp structure.
A metallic crystal crystallizes into a lattice containing a sequence of layers AB AB AB......Any packing of spheres leaves out voids in the lattice. What percentage of volume of this lattice is empty space?
Calculate the volume occupied by a particle in a simple cubic unit cell if the volume of the unit cell is 5.5 × 10−22 cm3.
What is the minimum number of spheres required to develop an octahedral void?
