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Karnataka Board PUCPUC Science 2nd PUC Class 12

PUC Science 2nd PUC Class 12 - Karnataka Board PUC Question Bank Solutions for Chemistry

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Chemistry
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Define azeotropes. 

[1] Solutions
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Draw the geometrical isomers of complex [Pt(NH3)2Cl2].

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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Write the equation involved in the acetylation of Salicylic acid.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Why does a solution containing non-volatile solute have higher boiling point than the pure solvent ?

[1] Solutions
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Write the names and structure of the monomers of the following polymers: 

Nylon-6, 6

[15] Polymers
Chapter: [15] Polymers
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Write the structure of the major product in each of the following reaction :

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
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How will you distinguish between the following pair of terms?

Tetrahedral and octahedral voids

[1] Solid State
Chapter: [1] Solid State
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What type of isomerism is exhibited by the complex [Co(en)3]3+?

(en = ethane-1,2-diamine)

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
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What type of deviation is shown by a mixture of ethanol and acetone? Give reason.

[1] Solutions
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Which of the following is a fibre? Nylon, neoprene, PVC

[15] Polymers
Chapter: [15] Polymers
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Define the following term:

Anomers 

[5] Coordination Compounds
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Write the structures of A, B and C in the following:

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
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If the radius of the octahedral void is r and the radius of the atoms in close packing is R, derive the relation between r and R.

[1] Solid State
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The vapour pressures of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. Find out the composition of the liquid mixture if the total vapour pressure is 600 mm Hg. Also, find the composition of the vapour phase.

[1] Solutions
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Vapour pressure of pure water at 298 K is 23.8 mm Hg. 50 g of urea (NH2CONH2) is dissolved in 850 g of water. Calculate the vapour pressure of water for this solution and its relative lowering.

[1] Solutions
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An aqueous solution of 2% non-volatile solute exerts a pressure of 1.004 bar at the normal boiling point of the solvent. What is the molar mass of the solute?

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The vapour pressure of water is 12.3 kPa at 300 K. Calculate vapour pressure of 1 molal solution of a non-volatile solute in it.

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Calculate the mass of a non-volatile solute (molar mass 40 g mol−1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.

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A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further, 18 g of water is then added to the solution and the new vapour pressure becomes 2.9 kPa at 298 K. Calculate:

  1. molar mass of the solute.
  2. vapour pressure of water at 298 K.
[1] Solutions
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100 g of liquid A (molar mass 140 g mol−1) was dissolved in 1000 g of liquid B (molar mass 180 g mol−1). The vapour pressure of pure liquid B was found to be 500 torr. Calculate the vapour pressure of pure liquid A and its vapour pressure in the solution if the total vapour pressure of the solution is 475 Torr.

[1] Solutions
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