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प्रश्न
Write Hardy-Sulze rules.
Write a note on Hardy–Schulze rule.
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उत्तर
- Generally, the greater the valency of the flocculating ion added, the greater is its power to cause precipitation. This is known as the Hardy–Schulze rule.
- In the coagulation of negative sol, the flocculating power follows the following order:
Al3+ > Ba2+ > Na+ - Similarly, in the coagulation of positive sol, the flocculating power is in the following order:
\[\ce{[Fe(CN)_6]^{4-} > PO_4^{3-} > SO_4^{2-} > Cl^-}\]
संबंधित प्रश्न
Write one difference in Multimolecular colloid and Associated colloid
Define the following with a suitable example, of each:
Gel
Define the term Electrophoresis.
Distinguish between lyophobic and lyophilic sols.
Write a note on Brownian motion.
What happens when a beam of light is passed through a colloidal sol.
Explain micelle formation in a soap solution.
Draw labelled diagram Tyndall effect.
Which of the following is multimolecular colloid?
Identify the CORRECT statement.
Identify the CORRECT statements from the following.
i. The colour of colloidal dispersion depends on size of colloidal particles.
ii. Tyndall effect is used to distinguish between colloidal dispersion and true solution.
iii. Eosin and congo red are examples of negatively charged sols.
Mist is a colloidal solution of ____________.
Which of the following is an example of liquid-liquid system?
The order of coagulating power of following ions in the coagulation of a positive sol is:
i. \[\ce{PO^{3-}_4}\]
ii. \[\ce{SO^{2-}_4}\]
iii. \[\ce{[Fe(CN)6]^{4-}}\]
iv. \[\ce{NO^-_3}\]
Which of the following is NOT true for lyophilic colloids?
Mixing of two oppositely charged sols leads to ____________.
Tyndall effect is observed due to ____________.
Froth is a colloidal solution of ____________.
The movement of colloidal particles towards respective electrode under electric field is called ______.
Some colloids are stable by their nature, i.e., gels, alloys, and solid foams. Gelatin and jellies are two common examples of a gel. The solid and liquid phases in a gel are interdispersed with both phases being continuous. In most systems, the major factor influencing the stability is the charge on the colloidal particles. If a particular ion is preferentially adsorbed on the surface of the particles, the particles in suspension will repel each other, thereby preventing the formation of aggregates that are larger than colloidal dimensions. The ion can be either positive or negative depending on the particular colloidal system, i.e., air bubbles accumulate negative ions, sulphur particles have a net negative charge in a sulphur sol, and the particles in a metal hydroxide sol are positively charged. Accumulation of charge on a surface is not an unusual phenomenon-dust is attracted to furniture surfaces by electrostatic forces. When salts are added to lyophobic colloidal systems the colloidal particles begin to form larger aggregates and a sediment forms as they settle. This phenomenon is called flocculation, and the suspension can be referred to as flocculated, or colloidally unstable. If the salt is removed, the suspension can usually be restored to its original state; this process is called deflocculation or peptization. The original and restored colloidal systems are called deflocculated, peptized, or stable sols.
Why does a small amount of salt have such a dramatic effect on the stability of a lyophobic colloidal system? The answer lies in an understanding of the attractive and repulsive forces that exist between colloidal particles. Van der Waals forces are responsible for the attractions, while the repulsive forces are due to the surface charge on the particles. In a stable colloid, the repulsive forces are of greater magnitude than the attractive forces. The magnitude of the electrical repulsion is diminished by addition of ionized salt, which allows the dispersed particles to aggregate and flocculate. River deltas provide an example of this behaviour. A delta is formed at the mouth of a river because the colloidal clay particles are flocculated when the freshwater mixes with the salt water of the ocean.
Colloidal solutions are stable due to ______.
What happens when electric field is applied to colloidal solution?
A colloid is formed by adding \[\ce{FeCl3}\] in excess of hot water. What will happen if excess sodium chloride is added to this colloid?
Why are some medicines more effective in the colloidal form?
How does the precipitation of colloidal smoke take place in Cottrell precipitator?
On the basis of Hardy-Schulze rule explain why the coagulating power of phosphate is higher than chloride.
For coagulating 200 ml of arsenious sulphide sol, 10 ml of 1 m NaCl solution is required find out the flocculation value of NaCl.
Blood may be purified by ______.
