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प्रश्न
Write a note on the Tyndall effect.
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उत्तर
- Tyndall observed that when light passes through a true solution, the path of light through it cannot be detected.
- However, if the light passes through a colloidal dispersion, the particles scatter some light in all directions and the path of the light through colloidal dispersion becomes visible to an observer standing at right angles to its path.
- The phenomenon of scattering of light by colloidal particles and making the path of light visible through the dispersion is referred to as the Tyndall effect and the bright cone of the light is called the Tyndall cone.
- The Tyndall effect is observed only when the following conditions are satisfied.
a. The diameter of the dispersed particles is not much smaller than the wavelength of light used.
b. The refractive indices of the dispersed phase and dispersion medium differ largely. - Significance of Tyndall effect:
a. It is useful in determining the number of particles in the colloidal system and their particle size.
b. It is used to distinguish between colloidal dispersion and true solution.
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संबंधित प्रश्न
Distinguish between lyophobic and lyophilic sols.
Identify the dispersed phase and dispersion medium in the following colloidal dispersions.
- milk
- blood
- printing ink
- fog
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Maximum coagulation power is in ____________.
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The movement of colloidal particles towards respective electrode under electric field is called ______.
Pumice stone is an example of ______.
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Why does a small amount of salt have such a dramatic effect on the stability of a lyophobic colloidal system? The answer lies in an understanding of the attractive and repulsive forces that exist between colloidal particles. Van der Waals forces are responsible for the attractions, while the repulsive forces are due to the surface charge on the particles. In a stable colloid, the repulsive forces are of greater magnitude than the attractive forces. The magnitude of the electrical repulsion is diminished by addition of ionized salt, which allows the dispersed particles to aggregate and flocculate. River deltas provide an example of this behaviour. A delta is formed at the mouth of a river because the colloidal clay particles are flocculated when the freshwater mixes with the salt water of the ocean.
Gelatin is a _________ colloidal system.
Some colloids are stable by their nature, i.e., gels, alloys, and solid foams. Gelatin and jellies are two common examples of a gel. The solid and liquid phases in a gel are interdispersed with both phases being continuous. In most systems, the major factor influencing the stability is the charge on the colloidal particles. If a particular ion is preferentially adsorbed on the surface of the particles, the particles in suspension will repel each other, thereby preventing the formation of aggregates that are larger than colloidal dimensions. The ion can be either positive or negative depending on the particular colloidal system, i.e., air bubbles accumulate negative ions, sulphur particles have a net negative charge in a sulphur sol, and the particles in a metal hydroxide sol are positively charged. Accumulation of charge on a surface is not an unusual phenomenon-dust is attracted to furniture surfaces by electrostatic forces. When salts are added to lyophobic colloidal systems the colloidal particles begin to form larger aggregates and a sediment forms as they settle. This phenomenon is called flocculation, and the suspension can be referred to as flocculated, or colloidally unstable. If the salt is removed, the suspension can usually be restored to its original state; this process is called deflocculation or peptization. The original and restored colloidal systems are called deflocculated, peptized, or stable sols.
Why does a small amount of salt have such a dramatic effect on the stability of a lyophobic colloidal system? The answer lies in an understanding of the attractive and repulsive forces that exist between colloidal particles. Van der Waals forces are responsible for the attractions, while the repulsive forces are due to the surface charge on the particles. In a stable colloid, the repulsive forces are of greater magnitude than the attractive forces. The magnitude of the electrical repulsion is diminished by addition of ionized salt, which allows the dispersed particles to aggregate and flocculate. River deltas provide an example of this behaviour. A delta is formed at the mouth of a river because the colloidal clay particles are flocculated when the freshwater mixes with the salt water of the ocean.
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Which of the following substances will precipitate the negatively charged emulsions?
(i) \[\ce{KCl}\]
(ii) glucose
(iii) urea
(iv) \[\ce{NaCl}\]
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Match the items of Column I and Column II.
| Column I | Column II |
| (i) Butter | (a) dispersion of liquid in liquid |
| (ii) Pumice stone | (b) dispersion of solid in liquid |
| (iii) Milk | (c) dispersion of gas in solid |
| (iv) Paints | (d) dispersion of liquid in solid |
Toluene is oxidised to benzoic acid by
The coagulation of 200 ML of position sol took place when 0.73 HCL was added to its without changing the volume much. The flocculation value of HCL for the colloid is.
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Which of the following is most powerful to coagulate the negative colloid?
Smoke is an example of ______.
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Identify the colloidal molecule containing hydrophilic head and hydrophobic tail within it.
